Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif

被引：25

作者：

Hao, Pengfei ^{[1
]}

Yang, Zhi ^{[1
]}

Ma, Xiaoli ^{[1
]}

Wang, Xiujuan ^{[1
]}

Liu, Zhihong ^{[1
]}

Roesky, Herbert W. ^{[2
]}

Sun, Kening ^{[1
]}

Li, Jiarong ^{[1
]}

Zhong, Mingdong ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 43期

基金：

高等学校博士学科点专项科研基金;

关键词：

ALUMINUM; PHOSPHONATES; PHOSPHATES; ROUTE; ALUMINOPHOSPHONATE; POLYMERIZATION; BETA;

D O I：

10.1039/c2dt31872e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of LAlH2 (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) (1) with diphenylsilanediol, phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with the Al-O-X (X = Si, P, C) motif of composition [LAl(mu-O)](2)Si(Ph)(2) (2), [LAl(mu-O)](2)PO(Ph) (3), LAl[OPO(Ph)(2)](2) (4), and LAl(mu-O)(2)(o-C6H4) (5), respectively. Compound 2 contains the Al-O-Si-O-Al heterotrimetallic dioxide chain. Compound 3 features an Al(mu-O)](2)P four-membered ring, while compound 4 exhibits a P-O-Al-O-P chain structure. Compound 5 contains the benzo-aluminum-dioxide organic-inorganic hybrid five-membered ring. Complexes 2, 3, 4, and 5 were characterized by NMR, elementary analysis, and single-crystal X-ray diffraction.

引用

页码：13520 / 13524

页数：5

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