The synthesis of a new class of polymer colloids with a low index of refraction

被引:17
作者
Hartl, W
ZhangHeider, X
机构
[1] Physikalische Chemie, Universität des Saarlandes, D 66123 Saarbrücken
关键词
polymer; colloids; synthesis;
D O I
10.1006/jcis.1996.4561
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper we report the synthesis of highly charged polymer colloids based on the monomer dihydroperfluorobutylacrylate with a refraction index of n(20)(D) = 1.37. By varying the polymerization parameters we could prepare polymer colloids in the size range of 70-500 nm. Removal of the excess ions in the suspensions leads to the formation of liquid-like or solid-like phases. (C) 1997 Academic Press
引用
收藏
页码:398 / 401
页数:4
相关论文
共 19 条
[1]   FLUORINE-CONTAINING POLYMERS .2. 1,1-DIHYDROPERFLUOROALKYL ACRYLATES - PREPARATION OF MONOMERS [J].
CODDING, DW ;
REID, TS ;
AHLBRECHT, AH ;
SMITH, GH ;
HUSTED, DR .
JOURNAL OF POLYMER SCIENCE, 1955, 15 (80) :515-519
[2]   STATIC AND DYNAMIC LIGHT-SCATTERING STUDY OF FLUORINATED POLYMER COLLOIDS WITH A CRYSTALLINE INTERNAL STRUCTURE [J].
DEGIORGIO, V ;
PIAZZA, R ;
BELLINI, T ;
VISCA, M .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1994, 48 :61-91
[3]  
Fitch RM, 1971, POLYM COLLOIDS
[4]   A RESCALED MSA STRUCTURE FACTOR FOR DILUTE CHARGED COLLOIDAL DISPERSIONS [J].
HANSEN, JP ;
HAYTER, JB .
MOLECULAR PHYSICS, 1982, 46 (03) :651-656
[5]  
HARTL W, 1988, J CHEM PHYS, V88, P7157, DOI 10.1063/1.454366
[6]  
HARTL W, 1995, J CHEM PHYS, V102, P6613, DOI 10.1063/1.469377
[7]   LIQUID-LIKE STRUCTURE OF CHARGED COLLOIDAL DISPERSIONS IN THE PRESENCE OF SCREENING IONS [J].
HARTL, W ;
VERSMOLD, H ;
WITTIG, U ;
MAROHN, V .
MOLECULAR PHYSICS, 1983, 50 (04) :815-823
[8]  
HARTL W, 1991, BER BUNSEN PHYS CHEM, V95, P1105
[9]  
HARTL W, IN PRESS
[10]   POLYMER LATTICES AS MODEL COLLOIDS [J].
HEARN, J ;
WILKINSON, MC ;
GOODALL, AR .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1981, 14 (2-3) :173-236