Rapid Injection NMR Reveals η3 'π-Allyl' CuIII Intermediates in Addition Reactions of Organocuprate Reagents

被引：24

作者：

Bertz, Steven H. ^{[1
]}

Hardin, Richard A. ^{[1
]}

Murphy, Michael D. ^{[1
]}

Ogle, Craig A. ^{[1
]}

Richter, Joshua D. ^{[1
]}

Thomas, Andy A. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Charlotte, NC 28223 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 23期

基金：

美国国家科学基金会;

关键词：

CONJUGATE ADDITION; GILMAN REAGENTS; ORGANOCOPPER; COPPER(I); MECHANISM; INSIGHTS;

D O I：

10.1021/ja3022363

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By using rapid injection NMR, it has now been possible to prepare and characterize the eta(3) 'pi-allyl' copper(III) intermediate that has been proposed for addition reactions of organocopper(I) reagents and alpha,beta-unsaturated carbonyl compounds.

引用

页码：9557 / 9560

页数：4

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