Synthesis of hybrid metal-organic frameworks of {FexMyM1-x-y′}-MIL-88B and the use of anions to control their structural features

被引:45
作者
Choi, Sora [1 ]
Cha, Wonhee [1 ]
Ji, Hoyeon [1 ]
Kim, Dooyoung [1 ]
Lee, Hee Jung [1 ]
Oh, Moonhyun [1 ]
机构
[1] Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
基金
新加坡国家研究基金会;
关键词
POROUS COORDINATION POLYMER; ZEOLITIC IMIDAZOLATE FRAMEWORK; CARBON-DIOXIDE CAPTURE; CO2; ADSORPTION; MOF; RECOGNITION; PARTICLES; POROSITY; TOPOLOGY; CRYSTALS;
D O I
10.1039/c6nr05463c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The controlled formation of metal-organic frameworks (MOFs) or coordination polymers (CPs) with suitable components and structural features is one of the most important themes in MOF research. In particular, the reliable preparation of hybrid MOFs containing more than two different kinds of metal ions or organic linkers and a comprehensive understanding of the structural flexibility of MOFs are the central issues for the production of MOFs with the desired properties. We report the synthesis of micro-sized hybrid MOF particles [also known as coordination polymer particles (CPPs)] containing two or three kinds of metal ions in each particle: {FexMyM1-x-y'}-MIL-88B (MIL stands for Materials of Institut Lavoisier, M and M' = Ga, Co, or Mn). Scanning electron microscopy images revealed the formation of well-defined uniform micro-sized hexagonal rods, and energy-dispersive X-ray spectroscopy and elemental mapping images verified the simultaneous incorporation of two or three kinds of metal ions within the CPPs. Interestingly, the structural features of CPPs made from MIL-88B were controlled by altering the anions involved in the structure. Incorporating large acetylacetonate anions within the structure resulted in the closed MIL-88B structure with a small cell volume. However, the open MIL-88B structure with a large cell volume was obtained when small chloride anions were incorporated. The intermediate semi-open MIL-88B structure was also prepared using nitrate anions. Three different structural forms of MIL-88B were verified by powder X-ray diffraction, whole pattern fitting, and thermogravimetric analysis.
引用
收藏
页码:16743 / 16751
页数:9
相关论文
共 61 条
[1]   Tuning MOF CO2 Adsorption Properties via Cation Exchange [J].
An, Jihyun ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (16) :5578-+
[2]   High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].
An, Jihyun ;
Geib, Steven J. ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+
[3]   Core-Double-Shell Fe3O4@Carbon@Poly(InIII-carboxylate) Microspheres: Cycloaddition of CO2 and Epoxides on Coordination Polymer Shells Constituted by lmidazolium-Derived AIIII-Salen Bifunctional Catalysts [J].
An, Qiao ;
Li, Zifeng ;
Graff, Robert ;
Guo, Jia ;
Gao, Haifeng ;
Wang, Changchun .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (08) :4969-4978
[4]   A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals [J].
Bae, Tae-Hyun ;
Lee, Jong Suk ;
Qiu, Wulin ;
Koros, William J. ;
Jones, Christopher W. ;
Nair, Sankar .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (51) :9863-9866
[5]   A bimodal anionic MOF: turn-off sensing of CuII and specific sensitization of EuIII [J].
Bhattacharyya, Sohini ;
Chakraborty, Anindita ;
Jayaramulu, Kolleboyina ;
Hazra, Arpan ;
Maji, Tapas Kumar .
CHEMICAL COMMUNICATIONS, 2014, 50 (88) :13567-13570
[6]   Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites [J].
Bloch, Eric D. ;
Queen, Wendy L. ;
Krishna, Rajamani ;
Zadrozny, Joseph M. ;
Brown, Craig M. ;
Long, Jeffrey R. .
SCIENCE, 2012, 335 (6076) :1606-1610
[7]   Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2 Complexes That Exhibit High-Temperature H2 Sorption and Chemical Reactivity [J].
Bohnsack, Alisha M. ;
Ibarra, Ilich A. ;
Bakhmutov, Vladimir I. ;
Lynch, Vincent M. ;
Humphrey, Simon M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (43) :16038-16041
[8]   Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites [J].
Britt, David ;
Furukawa, Hiroyasu ;
Wang, Bo ;
Glover, T. Grant ;
Yaghi, Omar M. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (49) :20637-20640
[9]   Hierarchical bicontinuous porosity in metal-organic frameworks templated from functional block co-oligomer micelles [J].
Cao, Shuai ;
Gody, Guillaume ;
Zhao, Wei ;
Perrier, Sebastien ;
Peng, Xiaoyu ;
Ducati, Caterina ;
Zhao, Dongyuan ;
Cheetham, Anthony K. .
CHEMICAL SCIENCE, 2013, 4 (09) :3573-3577
[10]   Selective metal substitution for the preparation of heterobimetallic microporous coordination polymers [J].
Caskey, Stephen R. ;
Matzger, Adam J. .
INORGANIC CHEMISTRY, 2008, 47 (18) :7942-7944