Visible-light photoredox-mediated oxidation of N-methyl tertiaryamines under catalyst free conditions: Direct synthesis of methylene-bridged bis-1,3-dicarbonyl compounds

被引：12

作者：

Dai, Xiao-Jun ^{[1
]}

Xu, Xiao-Liang ^{[1
]}

Cheng, Dong-Ping ^{[2
]}

Li, Xiao-Nian ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Inst Ind Catalysis, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China

[2] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2014年 / 25卷 / 04期

关键词：

Photochemistry; Oxidation; Aliphatic tertiaryamine; Catalyst free; ORGANIC-SYNTHESIS; AEROBIC OXIDATION; PHOTOCATALYSIS; ALKENES; FUNCTIONALIZATION; CYCLOADDITIONS; DERIVATIVES; COMPLEXES; ARYLATION; RADICALS;

D O I：

10.1016/j.cclet.2014.01.021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mediated by visible light-induced photoredox catalysis and free of other catalysts, a new and efficient synthesis of methylene-bridged bis-1,3-dicarbonyl derivatives has been developed. A variety of N-methyl tertiaryamines and 1,3-dicarbonyl compounds were investigated in this reaction. (C) 2014 Xiao-Liang Xu and Xiao-Nian Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：545 / 548

页数：4

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