Olefin metathesis in air

被引：36

作者：

Piola, Lorenzo ^{[1
]}

Nahra, Fady ^{[1
]}

Nolan, Steven P. ^{[2
]}

机构：

[1] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland

[2] King Saud Univ, Coll Sci, Chem Dept, Riyadh 11451, Saudi Arabia

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 11卷

关键词：

air stability; catalysis; olefin metathesis; RCM; ROMP; ruthenium; RING-CLOSING METATHESIS; RUTHENIUM-INDENYLIDENE COMPLEXES; TRANSFER RADICAL-ADDITION; N-HETEROCYCLIC CARBENES; CROSS-METATHESIS; ALKENE METATHESIS; SCHIFF-BASES; CATALYSTS; POLYMERIZATION; EFFICIENT;

D O I：

10.3762/bjoc.11.221

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Since the discovery and now widespread use of olefin metathesis, the evolution of metathesis catalysts towards air stability has become an area of significant interest. In this fascinating area of study, beginning with early systems making use of high oxidation state early transition metal centers that required strict exclusion of water and air, advances have been made to render catalysts more stable and yet more functional group tolerant. This review summarizes the major developments concerning catalytic systems directed towards water and air tolerance.

引用

页码：2038 / 2055

页数：18

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