Crystal Structures and Magnetic Properties of Two Phases from Imidazolate-bridged Copper(II) 4,6-Nonanedionate Complexes

被引:3
作者
Watanabe, Ryo [1 ]
Koyama, Nobumasa [1 ]
Nogami, Takashi [1 ]
Ishida, Takayuki [1 ]
Kogane, Tamizo [1 ]
机构
[1] Univ Electrocommun, Dept Appl Phys & Chem, Tokyo 1828585, Japan
关键词
TETRANUCLEAR COPPER(II); TRINUCLEAR; CHEMISTRY; MOIETIES; OXIDASES; LIGANDS; DESIGN; ZN; MN; CU;
D O I
10.1246/cl.2009.30
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A helical chain [Cu(dnbm)(mu-im)](n) and a tetrancuclear macrocycle [Cu(dnbm)([mu-im)](4) (Hdnbm = 4,6-nonanedione, Him = imidazole) were selectively prepared and structurally characterized. Their magnetic properties obeyed one-dimensional] chain and square models, respectively.
引用
收藏
页码:30 / 31
页数:2
相关论文
共 20 条
[1]   Infinite zig-zag and cyclic-tetranuclear isomeric imidazolate-bridged polynuclear copper(II) complexes: Magnetic properties, catalytic activity and electrospray mass and tandem mass spectrometry characterization [J].
Alves, WA ;
Cerchiaro, G ;
Paduan, A ;
Tomazela, DM ;
Eberlin, MN ;
Ferreira, AMD .
INORGANICA CHIMICA ACTA, 2005, 358 (13) :3581-3591
[2]   A trinuclear cyanamidonitrate-copper(II) complex bridged by imidazolato ligands [J].
Boca, R ;
Hvastijová, M ;
Kozísek, J ;
Valko, M ;
Ehrenberg, H ;
Fuess, H ;
Haase, W ;
Svoboda, I ;
Werner, R .
INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (06) :548-551
[3]   LINEAR MAGNETIC CHAINS WITH ANISOTROPIC COUPLING [J].
BONNER, JC ;
FISHER, ME .
PHYSICAL REVIEW, 1964, 135 (3A) :A640-+
[4]   AN IMIDAZOLATE-BRIDGED TETRANUCLEAR COPPER(II) COMPLEX - SYNTHESIS, MAGNETIC AND EPR STUDIES, AND CRYSTAL-STRUCTURE OF [L4CU4(IM)4](CLO4)42H2O (L = 1,4,7-TRIAZACYCLONONANE, IM = IMIDAZOLATE ANION) [J].
CHAUDHURI, P ;
KARPENSTEIN, I ;
WINTER, M ;
LENGEN, M ;
BUTZLAFF, C ;
BILL, E ;
TRAUTWEIN, AX ;
FLORKE, U ;
HAUPT, HJ .
INORGANIC CHEMISTRY, 1993, 32 (06) :888-894
[5]   ISOLATION OF A SPIN-FRUSTRATED IMIDAZOLATE-BRIDGED TRINUCLEAR COPPER(II) COMPLEX POTENTIALLY RELEVANT TO THE MULTICOPPER OXIDASES [J].
CHAUDHURI, P ;
KARPENSTEIN, I ;
WINTER, M ;
BUTZLAFF, C ;
BILL, E ;
TRAUTWEIN, AX ;
FLORKE, U ;
HAUPT, HJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (04) :321-322
[6]   A novel series of heterotrinuclear complexes involving imidazolate bridging Schiff's base ligands. Synthesis, crystal structure, and magnetic properties [J].
Colacio, E ;
Dominguez-Vera, JM ;
Ghazi, M ;
Kivekas, R ;
Klinga, M ;
Moreno, JM .
INORGANIC CHEMISTRY, 1998, 37 (12) :3040-3045
[7]   A rational design for imidazolate-bridged linear trinuclear compounds from mononuclear copper(II) complexes with 2-[((imidazol-2-ylmethylidene)amino)ethyl]pyridine (HL):: Syntheses, structures, and magnetic properties of [Cu(L)(hfac)M(hfac)2Cu(hfac)(L)] (M = ZnII, CuII, MnII) [J].
Colacio, E ;
Ghazi, M ;
Kivekäs, R ;
Klinga, M ;
Lloret, F ;
Moreno, JM .
INORGANIC CHEMISTRY, 2000, 39 (13) :2770-2776
[8]   Deprotonation and self-assembly of symmetric oxamidate-bridged dinuclear copper(II) complex involving imidazole moieties [J].
DominguezVera, JM ;
Galvez, N ;
Colacio, E ;
Cuesta, R ;
Costes, JP ;
Laurent, JP .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (06) :861-865
[9]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[10]   Synthesis and characterization of imidazolate-bridged polynuclear copper complexes [J].
Higa, Takumi ;
Moriya, Masaki ;
Shimazaki, Yuichi ;
Yajima, Tatsuo ;
Tani, Fumito ;
Karasawa, Satoru ;
Nakano, Motohiro ;
Naruta, Yoshinori ;
Yamauchi, Osamu .
INORGANICA CHIMICA ACTA, 2007, 360 (10) :3304-3313