Characterization of porous alkali-activated fly ash composite as a solid absorbent

被引:35
作者
Chindaprasirt, Prinya [1 ,2 ]
Rattanasak, Ubolluk [3 ]
机构
[1] Khon Kaen Univ, Fac Engn, Dept Civil Engn, Sustainable Infrastruct Res & Dev Ctr, Khon Kaen 40002, Thailand
[2] Royal Soc Thailand, Off Royal Soc, Bangkok 10300, Thailand
[3] Burapha Univ, Fac Sci, Dept Chem, Chon Buri 20131, Thailand
关键词
Porous alkali-activated fly ash; High-calcium fly ash; CO2; capture; Absorbent; CARBON-DIOXIDE; POWER-PLANT; ZEOLITE; 13X; CO2; CAPTURE; CEMENT; GEOPOLYMERS; ADSORPTION; ADSORBENT;
D O I
10.1016/j.ijggc.2019.03.011
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This research proposed the synthesis of porous alkali-activated fly ash (AA-fly ash) composites with a simple method for CO2 capture application. Two types of foaming agents, viz., zinc stearate/H2O2 and Al powder, were used to produce pores in the materials. Results revealed that porous AA-fly ash composite with a density of 1 g/cm(3) could be fabricated. Using Al powder, the method obtained a porous AA-fly ash paste with surface area of 36 m(2)/g, values which were higher than those of zinc stearate/H2O2. The AA-fly ash composite was crushed and applied as the CO2 gas absorbent. The absorption rate was 0.12 g CO2 per gram of porous AA-fly ash composite, suggesting that the porous AA-fly ash composite can be used as a solid absorbent. In addition, the production process is simple and cost effective.
引用
收藏
页码:30 / 35
页数:6
相关论文
共 31 条
[1]  
ASTM International, 2017, C18817 ASTM
[2]   Thermal behaviour of inorganic geopolymers and composites derived from sodium polysialate [J].
Barbosa, VFF ;
MacKenzie, KJD .
MATERIALS RESEARCH BULLETIN, 2003, 38 (02) :319-331
[3]   Adsorption of CO2 on nitrogen-enriched activated carbon and zeolite 13X [J].
Bezerra, Diogo P. ;
Oliveira, Ronan S. ;
Vieira, Rodrigo S. ;
Cavalcante, Celio L., Jr. ;
Azevedo, Diana C. S. .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2011, 17 (01) :235-246
[4]   CO2 Capture Technologies for Cement Industry [J].
Bosoaga, Adina ;
Masek, Ondrej ;
Oakey, John E. .
GREENHOUSE GAS CONTROL TECHNOLOGIES 9, 2009, 1 (01) :133-140
[5]  
Cao Y.F., 2017, 2017 IEEE C EN INT, DOI 10.12783/dteees/icepe2017/11891
[6]   Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13X at high pressures [J].
Cavenati, S ;
Grande, CA ;
Rodrigues, AE .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (04) :1095-1101
[7]   Characterization of the high-calcium fly ash geopolymer mortar with hot-weather curing systems for sustainable application [J].
Chindaprasirt, Prinya ;
Rattanasak, Ubolluk .
ADVANCED POWDER TECHNOLOGY, 2017, 28 (09) :2317-2324
[8]   Strength and resistance to sulfate and sulfuric acid of ground fluidized bed combustion fly ash-silica fume alkali-activated composite [J].
Chindaprasirt, Prinya ;
Paisitsrisawat, Pattanapong ;
Rattanasak, Ubolluk .
ADVANCED POWDER TECHNOLOGY, 2014, 25 (03) :1087-1093
[9]   Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources [J].
Choi, Sunho ;
Drese, Jeffrey H. ;
Jones, Christopher W. .
CHEMSUSCHEM, 2009, 2 (09) :796-854
[10]   GEOPOLYMERS - INORGANIC POLYMERIC NEW MATERIALS [J].
DAVIDOVITS, J .
JOURNAL OF THERMAL ANALYSIS, 1991, 37 (08) :1633-1656