Novel approach to fabricate a stable superhydrophobic polycarbonate

被引:24
作者
Sabry, Raad S. [1 ]
Al-Mosawi, Muntazer I. [1 ]
机构
[1] Al Mustansiriyah Univ, Coll Sci, Phys Dept, Baghdad, Iraq
关键词
Superhydrophobic surfaces; phase separation; hierarchical structures; polycarbonate; solvent/non-solvent; THERMAL-DEGRADATION; SURFACES; TRANSFORMATION; POLYMERS; FIBERS; LOTUS;
D O I
10.1080/02670844.2016.1270620
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A novel approach to fabricating a stable superhydrophobic PC using a phase separation method and selecting a solvent/non-solvent without requiring any surface chemical modification and high chemical stability was proposed in this paper. A systematic study of the dependence of surface morphology on the acetone/DMF solvent mixture treatment was conducted. Resulting surfaces demonstrated that the water CA of the superhydrophobic PC surface was 160 +/- 2 degrees. FESEM showed that the surface structure comprised branches or petals outside the 'plant seabeds', which have microflowers that offer nanoscaled roughness on the surface with a hierarchical micro-/nano-binary formation. All samples were maintained at 10-40 degrees C in ambient atmosphere for 5 h to 4 months to test the stability of the surface. The CAs were measured for each condition with very little change observed. In addition, the PC surface remained superhydrophobic without any contamination after water was sprayed on it.
引用
收藏
页码:151 / 157
页数:7
相关论文
共 22 条
[1]   Kinetic analysis of thermal degradation of recycled polycarbonate/acrylonitrile-butadiene-styrene mixtures from waste electric and electronic equipment [J].
Balart, R ;
Sánchez, L ;
López, J ;
Jiménez, A .
POLYMER DEGRADATION AND STABILITY, 2006, 91 (03) :527-534
[2]   Wettability of porous surfaces. [J].
Cassie, ABD ;
Baxter, S .
TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 :0546-0550
[3]   Effect of metal chlorides on thermal degradation of (waste) polycarbonate [J].
Chiu, SJ ;
Chen, SH ;
Tsai, CT .
WASTE MANAGEMENT, 2006, 26 (03) :252-259
[4]   Hierarchical polymeric textures via solvent-induced phase transformation: A single-step production of large-area superhydrophobic surfaces [J].
Cui, Yuehua ;
Paxson, Adam T. ;
Smyth, Katherine M. ;
Varanasi, Kripa K. .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 394 :8-13
[5]   Bisphenol A-based polycarbonates: characterization of commercial samples [J].
Delpech, MC ;
Coutinho, FMB ;
Habibe, MES .
POLYMER TESTING, 2002, 21 (02) :155-161
[6]   Transformation of a simple plastic into a superhydrophobic surface [J].
Erbil, HY ;
Demirel, AL ;
Avci, Y ;
Mert, O .
SCIENCE, 2003, 299 (5611) :1377-1380
[7]   Formation of Nanoporous Polycarbonate Surfaces and Their Chemical Modification for Superhydrophobicity [J].
Go, Seungcheol ;
Han, Moonhee ;
Ahn, Younghyun .
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2012, 33 (11) :3899-3902
[8]   Hydrophobic modification of polycarbonate for reproducible and stable formation of biocompatible microparticles [J].
Jankowski, Pawel ;
Ogonczyk, Dominika ;
Kosinski, Andrzej ;
Lisowski, Wojciech ;
Garstecki, Piotr .
LAB ON A CHIP, 2011, 11 (04) :748-752
[9]   Preparation of a super-hydrophobic poly(vinyl chloride) surface via solvent-nonsolvent coating [J].
Li, XH ;
Chen, GM ;
Ma, YM ;
Feng, L ;
Zhao, HZ ;
Jiang, L ;
Wang, FS .
POLYMER, 2006, 47 (02) :506-509
[10]   Decorated electrospun fibers exhibiting superhydrophobicity [J].
Ma, Minglin ;
Gupta, Malancha ;
Li, Zhi ;
Zhai, Lei ;
Gleason, Karen K. ;
Cohen, Robert E. ;
Rubner, Michael F. ;
Rutledge, Gregory C. .
ADVANCED MATERIALS, 2007, 19 (02) :255-+