Preparation of Vinyl Silyl Ethers and Disiloxanes via the Silyl-Heck Reaction of Silyl Ditriflates

被引：81

作者：

Martin, Sara E. S. ^{[1
]}

Watson, Donald A. ^{[1
]}

机构：

[1] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 36期

基金：

美国国家科学基金会;

关键词：

CROSS-COUPLING REACTIONS; SILICON; SUBSTITUENTS; VINYLSILANES; METATHESIS; ALKENES; OLEFINS;

D O I：

10.1021/ja407748z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vinyl silyl ether substrates in an efficient and direct manner with complete regiomeric and geometric selectivity.

引用

页码：13330 / 13333

页数：4

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