The Intermetallic Compound ZnPd and Its Role in Methanol Steam Reforming

被引：108

作者：

Armbruester, M. ^{[1
]}

Behrens, M. ^{[2
]}

Foettinger, K. ^{[3
]}

Friedrich, M. ^{[1
]}

Gaudry, E. ^{[4
]}

Matam, S. K. ^{[5
]}

Sharma, H. R. ^{[6
]}

机构：

[1] Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany

[2] Max Planck Gesell, Fritz Haber Inst, Inorgan Chem Dept, Berlin, Germany

[3] Vienna Univ Technol, Inst Mat Chem, A-1040 Vienna, Austria

[4] Univ Lorraine, CNRS, UMR 7198, Inst Jean Lamour, Nancy, France

[5] Empa, Swiss Fed Labs Mat Sci & Technol, Lab Solid State Chem & Catalysis, Dubendorf, Switzerland

[6] Univ Liverpool, Dept Phys, Liverpool L69 3BX, Merseyside, England

来源：

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2013年 / 55卷 / 03期

关键词：

Chemical properties; Hydrogen generation; Intermetallic compound; Methanol steam reforming; PdZn; Physical properties; SUPPORTED PD CATALYSTS; PALLADIUM-BASED ALLOY; NEAR-SURFACE ALLOYS; IN-SITU XPS; HYDROGEN-PRODUCTION; PD/ZNO CATALYST; CO ADSORPTION; PARTIAL OXIDATION; X-RAY; SELECTIVE HYDROGENATION;

D O I：

10.1080/01614940.2013.796192

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rich literature about the intermetallic compound ZnPd as well as several ZnPd near-surface intermetallic phases is reviewed. ZnPd is frequently observed in different catalytic reactions triggering this review in order to collect the knowledge about the compound. The review addresses the chemical and physical properties of the compound and relates these comprehensively to the catalytic properties of ZnPd in methanol steam reformingan interesting reaction to release hydrogen for a future hydrogen-based energy infrastructure from water/methanol mixtures. The broad scope of the review covers experimental work as well as quantum chemical calculations on a variety of Pd-Zn materials, aiming at covering all relevant literature to derive a sound state-of-the-art picture of the understanding gained so far.

引用

页码：289 / 367

页数：79

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