3-Amino-fluorene-2,4-dicarbonitriles (AFDCs) as Photocatalysts for the Decarboxylative Arylation of α-Amino Acids and α-Oxy Acids with Arylnitriles

被引：40
|
作者：
Chen, Yiyang [1 ]
Lu, Ping [1 ]
Wang, Yanguang [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
来源：
ORGANIC LETTERS | 2019年 / 21卷 / 07期
基金：
中国国家自然科学基金;
关键词：
ANTI-MARKOVNIKOV HYDROAMINATION; LIGHT PHOTOREDOX CATALYSIS; VISIBLE-LIGHT; ELECTROCHEMICAL OXIDATION; CARBOXYLIC-ACIDS;
D O I：
10.1021/acs.orglett.9b00443
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1-(4-(9H-Carbazol-9-yl)phenyl)-3-amino-9H-fluorene-2,4-dicarbonitrile as a new photocatalyst for the decarboxylative cross-coupling reaction of alpha-amino acids or alpha-oxy carboxylic acids with arylnitriles is described. This light-driven reaction enables a variety of benzylic amines and ethers to be prepared from readily available starting materials under mild conditions.
引用
收藏
页码：2130 / 2133
页数：4
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