3-Amino-fluorene-2,4-dicarbonitriles (AFDCs) as Photocatalysts for the Decarboxylative Arylation of α-Amino Acids and α-Oxy Acids with Arylnitriles

被引：40

作者：

Chen, Yiyang ^{[1
]}

Lu, Ping ^{[1
]}

Wang, Yanguang ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

来源：

ORGANIC LETTERS | 2019年 / 21卷 / 07期

基金：

中国国家自然科学基金;

关键词：

ANTI-MARKOVNIKOV HYDROAMINATION; LIGHT PHOTOREDOX CATALYSIS; VISIBLE-LIGHT; ELECTROCHEMICAL OXIDATION; CARBOXYLIC-ACIDS;

D O I：

10.1021/acs.orglett.9b00443

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-(4-(9H-Carbazol-9-yl)phenyl)-3-amino-9H-fluorene-2,4-dicarbonitrile as a new photocatalyst for the decarboxylative cross-coupling reaction of alpha-amino acids or alpha-oxy carboxylic acids with arylnitriles is described. This light-driven reaction enables a variety of benzylic amines and ethers to be prepared from readily available starting materials under mild conditions.

引用

页码：2130 / 2133

页数：4

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