3-Amino-fluorene-2,4-dicarbonitriles (AFDCs) as Photocatalysts for the Decarboxylative Arylation of α-Amino Acids and α-Oxy Acids with Arylnitriles

被引：40
作者：
Chen, Yiyang [1 ]
Lu, Ping [1 ]
Wang, Yanguang [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
来源：
ORGANIC LETTERS | 2019年 / 21卷 / 07期
基金：
中国国家自然科学基金;
关键词：
ANTI-MARKOVNIKOV HYDROAMINATION; LIGHT PHOTOREDOX CATALYSIS; VISIBLE-LIGHT; ELECTROCHEMICAL OXIDATION; CARBOXYLIC-ACIDS;
D O I：
10.1021/acs.orglett.9b00443
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1-(4-(9H-Carbazol-9-yl)phenyl)-3-amino-9H-fluorene-2,4-dicarbonitrile as a new photocatalyst for the decarboxylative cross-coupling reaction of alpha-amino acids or alpha-oxy carboxylic acids with arylnitriles is described. This light-driven reaction enables a variety of benzylic amines and ethers to be prepared from readily available starting materials under mild conditions.
引用
收藏
页码：2130 / 2133
页数：4
相关论文
共 42 条
  • [1] Homolytic and heterolytic radical cleavage in the Kolbe reaction -: Electrochemical oxidation of arylmethyl carboxylate ions
    Andrieux, CP
    Gonzalez, F
    Savéant, JM
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 498 (1-2): : 171 - 180
  • [2] Controlled Fluoroalkylation Reactions by Visible-Light Photoredox Catalysis
    Chatterjee, Tanmay
    Iqbal, Naeem
    You, Youngmin
    Cho, Eun Jin
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (10) : 2284 - 2294
  • [3] Exploration of Visible-Light Photocatalysis in Heterocycle Synthesis and Functionalization: Reaction Design and Beyond
    Chen, Jia-Rong
    Hu, Xiao-Qiang
    Lu, Liang-Qiu
    Xiao, Wen-Jing
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (09) : 1911 - 1923
  • [4] Synthesis and properties of 1-(4-aminophenyl)-2,4-dicyano-3-diethylamino-9,9-diethylfluorenes: Potential fluorescent material
    Chen, Xiao-Hang
    Zhao, Zujin
    Liu, Yang
    Lu, Ping
    Wang, Yan-Guang
    [J]. CHEMISTRY LETTERS, 2008, 37 (06) : 570 - 571
  • [5] Polymorphism-dependent emissions of two phenoxazine derivatives
    Chen, Yiyang
    Peng, Zhixing
    Tao, Yuhan
    Wang, Zaibin
    Lu, Ping
    Wang, Yanguang
    [J]. DYES AND PIGMENTS, 2019, 161 (44-50) : 44 - 50
  • [6] Parallel synthesis of strongly fluorescent polysubstituted 2,6-dicyanoanilines via microwave-promoted multicomponent reaction
    Cui, SL
    Lin, XF
    Wang, YG
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (07) : 2866 - 2869
  • [7] Bifunctional Photocatalysts for Enantioselective Aerobic Oxidation of β-Ketoesters
    Ding, Wei
    Lu, Liang-Qiu
    Quan-Quan Zhou
    Wei, Yi
    Chen, Jia-Rong
    Xiao, Wen-Jing
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (01) : 63 - 66
  • [8] Electrochemical oxidation of tetrabutylammonium salts of aliphatic carboxylic acids in acetonitrile
    Galicia, M
    González, FJ
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (03) : D46 - D50
  • [9] New catalytic transformations of carboxylic acids
    Goossen, Lukas J.
    Goossen, Kaethe
    Rodriguez, Nuria
    Blanchot, Mathieu
    Linder, Christophe
    Zimmermann, Bettina
    [J]. PURE AND APPLIED CHEMISTRY, 2008, 80 (08) : 1725 - 1733
  • [10] Direct Catalytic Anti-Markovnikov Hydroetherification of Alkenols
    Hamilton, David S.
    Nicewicz, David A.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (45) : 18577 - 18580
12345