Effective purge method with addition of hydrogen on the cathode side for cold start in PEM fuel cell

被引:60
作者
Kim, Sung Il [1 ]
Lee, Nam Woo [2 ]
Kim, Young Sang [1 ]
Kim, Min Soo [1 ]
机构
[1] Seoul Natl Univ, Sch Mech & Aerosp Engn, Div WCU Multiscale Mech Design, Seoul 151744, South Korea
[2] Hyundai Kia Motors, Fuel Cell Vehicle Team 2, Ecotechnol Ctr, Gyeonggi 446912, South Korea
基金
新加坡国家研究基金会;
关键词
Purge; Polymer electrolyte membrane fuel cell; Hydrogen addition purge method; Gas diffusion layer; Cold start; WATER REMOVAL; GAS; TEMPERATURE; PEFC;
D O I
10.1016/j.ijhydene.2013.06.101
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The purge process is essential for successful cold start of fuel cell vehicles during winter, and it plays an important role in the removal of the residual water inside the fuel cell in a short time. In this study, a new purge method is introduced by adding a small amount of hydrogen to the cathode gas flow in order to increase the purge performance. The experimental results demonstrate that the hydrogen addition purge method is very effective in removing the residual water near the catalyst layer. The water removal is verified by measuring the resistance of the fuel cell, dew point temperature of the outlet purge gas, and weights of the membrane electrolyte assembly (MEA) and gas diffusion layer (GDL). In addition, the image of the GDL after the purge process is captured to show the advantage of the hydrogen addition purge method. Cold start experiments are also conducted after the optimal purge process. It is also found that the degradation of the catalyst layer is not serious after the hydrogen addition purge process. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:11357 / 11369
页数:13
相关论文
共 20 条
[1]   Effect of material properties on evaporative water removal from polymer electrolyte fuel cell diffusion media [J].
Cho, Kyu Taek ;
Mench, Matthew M. .
JOURNAL OF POWER SOURCES, 2010, 195 (19) :6748-6757
[2]   Fundamental characterization of evaporative water removal from fuel cell diffusion media [J].
Cho, Kyu Taek ;
Mench, Matthew M. .
JOURNAL OF POWER SOURCES, 2010, 195 (12) :3858-3869
[3]   Characteristics of subzero startup and water/ice formation on the catalyst layer in a polymer electrolyte fuel cell [J].
Ge, Shanhai ;
Wang, Chao-Yang .
ELECTROCHIMICA ACTA, 2007, 52 (14) :4825-4835
[4]   A NEW APPROACH TO THE PROBLEM OF CARBON-MONOXIDE POISONING IN FUEL-CELLS OPERATING AT LOW-TEMPERATURES [J].
GOTTESFELD, S ;
PAFFORD, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (10) :2651-2652
[5]   Modeling of assisted cold start processes with anode catalytic hydrogen-oxygen reaction in proton exchange membrane fuel cell [J].
Guo, Qian ;
Luo, Yueqi ;
Jiao, Kui .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (02) :1004-1015
[6]   Cold start analysis of polymer electrolyte membrane fuel cells [J].
Jiao, Kui ;
Li, Xianguo .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (10) :5077-5094
[7]   Effects of various operating and initial conditions on cold start performance of polymer electrolyte membrane fuel cells [J].
Jiao, Kui ;
Li, Xianguo .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (19) :8171-8184
[8]   Experimental study on mitigating the cathode flooding at low temperature by adding hydrogen to the cathode reactant gas in PEM fuel cell [J].
Kim, Sung Il ;
Baik, Kyung Don ;
Kim, Beom Jun ;
Lee, Nam Woo ;
Kim, Min Soo .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (03) :1544-1552
[9]   Water removal characteristics of proton exchange membrane fuel cells using a dry gas purging method [J].
Lee, Sang-Yeop ;
Kim, Sang-Uk ;
Kim, Hyoung-Juhn ;
Jang, Jong Hyun ;
Oh, In-Hwan ;
Cho, Eun Ae ;
Hong, Seong-Ahn ;
Ko, Jaejun ;
Lim, Tae-Won ;
Lee, Kwan-Young ;
Lim, Tae-Hoon .
JOURNAL OF POWER SOURCES, 2008, 180 (02) :784-790
[10]   A REVIEW OF EJECTOR TECHNOLOGY FOR REFRIGERATION APPLICATIONS [J].
Little, Adrienne B. ;
Garimella, Srinivas .
INTERNATIONAL JOURNAL OF AIR-CONDITIONING AND REFRIGERATION, 2011, 19 (01) :1-15