Linear variational Diophantine techniques in mass balance of chemical reactions

被引：7

作者：

Balasubramanian, K

机构：

[1] Univ Calif Davis, Dept Appl Sci, Livermore, CA 94550 USA

[2] Lawrence Livermore Natl Lab, Chem & Mat Sci Directorate, Livermore, CA 94550 USA

[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Glenn T Seaborg Ctr, Berkeley, CA 94720 USA

来源：

JOURNAL OF MATHEMATICAL CHEMISTRY | 2001年 / 30卷 / 02期

基金：

美国国家科学基金会;

关键词：

Diophantine techniques; balancing chemical reactions; linear variation; thermodynamic functional;

D O I：

10.1023/A:1017979821326

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Linear algebraic techniques based on minimization of thermodynamic functional and/or other constraints are illustrated for mass balance of chemical reactions that do not exhibit stoichiometrically unique solutions in the linear algebraic vector space. The techniques demonstrate elegant casting of chemical equations in terms of generalized linear Diophantine matrices and generalized elimination and variational schemes.

引用

页码：219 / 225

页数：7