Magnetically recyclable Cu-BTC@Fe3O4-catalyzed synthesis of aryl a-chlorobenzyl ketones

被引：1
作者：
Wang, Liang [1 ]
Fan, Ya-Juan [1 ]
Sun, Yu -Tao [1 ]
He, Xin [1 ]
机构：
[1] Changzhou Vocat Inst Engn, Sch Chem & Pharmaceut Engn, Changzhou 213164, Peoples R China
来源：
MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 06期
关键词：
magnetic catalyst; metal-organic frameworks; a-chlorobenzyl ketones; radical reactions; arenediazonium salts; arylacetylenes; ALPHA-CHLORO; CATALYSIS; ALDEHYDES; ALCOHOLS;
D O I：
10.1016/j.mencom.2022.11.031
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic framework (MOF) composite, viz. Cu-BTC@Fe3O4 (BTC is 1,3,5-benzenetricarboxylate), was prepared and utilized for the synthesis of aryl a-chlorobenzyl ketones from arenediazonium salts and arylacetylenes in moderate to good yields. This reaction proceeded via a radical domino process. The catalyst could be readily recovered with an external permanent magnet, with slight decrease in its activity after successive six runs.
引用
收藏
页码：801 / 803
页数：3
相关论文
共 17 条
  • [1] A magnetic copper organic framework material as an efficient and recyclable catalyst for the synthesis of 1,2,3-triazole derivatives
    Arefi, Elham
    Khojastehnezhad, Amir
    Shiri, Ali
    [J]. SCIENTIFIC REPORTS, 2021, 11 (01)
  • [2] α-Haloaldehydes: versatile building blocks for natural product synthesis
    Britton, Robert
    Kang, Baldip
    [J]. NATURAL PRODUCT REPORTS, 2013, 30 (02) : 227 - 236
  • [3] Shaping of Metal-Organic Frameworks: From Fluid to Shaped Bodies and Robust Foams
    Chen, Yifa
    Huang, Xianqiang
    Zhang, Shenghan
    Li, Siqing
    Cao, Sijia
    Pei, Xiaokun
    Zhou, Junwen
    Feng, Xiao
    Wang, Bo
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (34) : 10810 - 10813
  • [4] Bronsted Acidity in Metal-Organic Frameworks
    Jiang, Juncong
    Yaghi, Omar M.
    [J]. CHEMICAL REVIEWS, 2015, 115 (14) : 6966 - 6997
  • [5] Direct Conversion of Alcohols to α-Chloro Aldehydes and α-Chloro Ketones
    Jing, Yuanyuan
    Daniliuc, Constantin G.
    Studer, Armido
    [J]. ORGANIC LETTERS, 2014, 16 (18) : 4932 - 4935
  • [6] ONE-POT SYNTHESIS OF ALPHA-CHLORO KETONES FROM SECONDARY ALCOHOLS USING N,N-DICHLORO-PARA-TOLUENESULFONAMIDE
    KIM, YH
    LEE, IS
    LIM, SC
    [J]. CHEMISTRY LETTERS, 1990, (07) : 1125 - 1128
  • [7] Metal-organic framework materials as catalysts
    Lee, JeongYong
    Farha, Omar K.
    Roberts, John
    Scheidt, Karl A.
    Nguyen, SonBinh T.
    Hupp, Joseph T.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) : 1450 - 1459
  • [8] Bridging homogeneous and heterogeneous catalysis with MOFs "Click" reactions with Cu-MOF catalysts
    Luz, I.
    Llabres i Xamena, F. X.
    Corma, A.
    [J]. JOURNAL OF CATALYSIS, 2010, 276 (01) : 134 - 140
  • [9] A visible-light-induced chemoselective radical/oxidative addition domino process to access α-chloro and α-alkoxy aryl ketones
    Niu, Teng-fei
    Jiang, Ding-yun
    Li, Si-yuan
    Ni, Bang-qing
    Wang, Liang
    [J]. CHEMICAL COMMUNICATIONS, 2016, 52 (89) : 13105 - 13108
  • [10] Strategies for catalytic asymmetric electrophilic a halogenation of carbonyl compounds
    Oestreich, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (16) : 2324 - 2327
12