Synthesis of poly(methyl methacrylate) nanoparticles via differential microemulsion polymerization

被引：29
|
作者：
Yuan, Liang [1 ]
Wang, Yun [2 ]
Pan, Maozhi [2 ]
Rempel, Garry L. [1 ,3 ]
Pan, Qinmin [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China
[2] Zhejiang Fangyuan Reflect Mat Co, Taizhou 318000, Zhejiang, Peoples R China
[3] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
来源：
EUROPEAN POLYMER JOURNAL | 2013年 / 49卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Particle size; Polymer nanoparticles; Poly(methyl methacrylate); Differential microemulsion polymerization; METHYL-METHACRYLATE; PARTICLES; EMULSION; POLYSTYRENE;
D O I：
10.1016/j.eurpolymj.2012.10.005
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(methyl methacrylate) nanoparticles are synthesized via differential microemulsion polymerization, where the monomers in the reaction system are kept at very low concentrations by continuous differential addition. The effects of various reaction conditions, such as initiator, surfactants, reaction temperature and monomer loadings, on the particle size and molecular weight have been investigated. The effects of initiator and reaction temperature on latex particle numbers and polymer chain numbers within the particles were also investigated. It was observed that the dependence of particle size on reaction temperature and initiator concentration was non-monotonic. The optimized conditions were screened to prepare nanoparticles with the smallest size. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：41 / 48
页数：8
相关论文
共 50 条
  • [41] Mechanism of microemulsion polymerization of methyl methacrylate: Experimental evidence
    Roy, S
    Devi, S
    JOURNAL OF APPLIED POLYMER SCIENCE, 1996, 62 (10) : 1509 - 1516
  • [42] INFLUENCE OF CONDITIONS OF SYNTHESIS OF POLY(METHYL METHACRYLATE ON THE HEAT OF POLYMERIZATION
    KARAPETYAN, ZA
    ATOVMYAN, YG
    ROSHCHUPKIN, VP
    SMIRNOV, BR
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1983, 25 (02): : 303 - 308
  • [43] Poly(methyl methacrylate) nanoparticles prepared through microwave emulsion polymerization
    Bao, JJ
    Zhang, AM
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 93 (06) : 2815 - 2820
  • [44] Poly(methyl methacrylate) nanoparticles prepared through microwave emulsion polymerization
    Bao, J. (jjbao2000@163.com), 1600, John Wiley and Sons Inc. (93):
  • [45] Production of nanoparticles of methyl methacrylate and butyl methacrylate copolymers by microemulsion polymerization in the presence of malefic acid terminated poly(N-acetylethylenimine) macromonomers as cosurfactant
    Babaç, C
    Güven, G
    David, G
    Simionescu, BC
    Piskin, E
    EUROPEAN POLYMER JOURNAL, 2004, 40 (08) : 1947 - 1952
  • [46] SYNTHESIS OF POLY(METHYL METHACRYLATE) MACROMER BY GROUP TRANSFER POLYMERIZATION AND POLYMERIZATION OF THE MACROMER
    ASAMI, R
    KONDO, Y
    TAKAKI, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 191 - POLY
  • [47] Synthesis of poly(methyl methacrylate) labeled with fluorescein moieties via atom transfer radical polymerization
    Li, Gang
    Zhu, Xiulin
    Cheng, Zhenping
    Zhang, Wei
    Sun, Bin
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2008, 45 (04): : 328 - 334
  • [48] Synthesis of poly(methyl methacrylate) labeled with fluorescein moieties via atom transfer radical polymerization
    Li, Gang
    Zhu, Xiulin
    Cheng, Zhenping
    Zhang, Wei
    Sun, Bin
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2008, 45 (06): : 495 - 501
  • [49] Effect of Modification of Silver Nanoparticles on the Preparation of Poly(methyl methacrylate)/Silver Microspheres via Suspension Polymerization
    Ji, Byung Chul
    Lee, Eun Mi
    Yeum, Jeong Hyun
    POLYMER-KOREA, 2010, 34 (04) : 341 - 345
  • [50] Encapsulation of Magnetic Nanoparticles and Copaíba Oil in Poly(methyl methacrylate) Nanoparticles via Miniemulsion Polymerization for Biomedical Application
    Cordeiro, Arthur P.
    Feuser, Paulo E.
    Araújo, Pedro H. H.
    Sayer, Claudia
    Macromolecular Symposia, 2020, 394 (01):
12345