Superhydrophobicity and regeneration of PVDF/SiO2 composite films

被引:23
作者
Liu, Tao [1 ]
Li, Xianfeng [1 ]
Wang, Daohui [1 ]
Huang, Qinglin [1 ]
Liu, Zhen [1 ]
Li, Nana [1 ]
Xiao, Changfa [1 ]
机构
[1] Tianjin Polytech Univ, Sch Mat Sci & Engn, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China
基金
中国国家自然科学基金;
关键词
Superhydrophobicity; Regeneration; Composite film; Polyvinylidene fluoride (PVDF); SiO2; nanoparticles; ROBUST SUPERHYDROPHOBICITY; NANOSTRUCTURED SURFACES; EASY-REPAIRABILITY; ICE ADHESION; NANOPARTICLES; COATINGS; FABRICATION; DURABILITY; DROPLET; FIBERS;
D O I
10.1016/j.apsusc.2016.11.184
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Superhydrophobicity of polymers is easily destroyed by careless touching due to the softness of microstructures. In this study, based on a well-constructed polyvinylidene fluoride (PVDF) surface, a novel superhydrophobic PVDF/SiO2 composite film was fabricated by adding hydrophobic SiO2 nanopartide and solvent into a coagulation bath. The water contact angle of the composite film reached 162.3 and the sliding angle was as low as 1.5. More importantly, the composite film could be regenerated only through immersing the composite film in the designed regeneration agent. The composition of the designed regeneration agent ensured that SiO2 nanoparticles were firmly adhered on the film surface even under the ultrasonic cleaning. Hence, the superhydrophobicity and self-cleaing property could be regenerated and maintained effectively, and moreover, these propeties could resist a proper pressure. In addition, after many rubbing-regenerating cycles, the regeneration method was still valid. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:1443 / 1449
页数:7
相关论文
共 33 条
[1]  
Azimi G, 2013, NAT MATER, V12, P315, DOI [10.1038/NMAT3545, 10.1038/nmat3545]
[2]   Robust Superhydrophobicity in Large-Area Nanostructured Surfaces Defined by Block-Copolymer Self Assembly [J].
Checco, Antonio ;
Rahman, Atikur ;
Black, Charles T. .
ADVANCED MATERIALS, 2014, 26 (06) :886-891
[3]   States of a Water Droplet on Nanostructured Surfaces [J].
Chen, Shuai ;
Wang, Jiadao ;
Chen, Darong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (32) :18529-18536
[4]   Effects of geometric parameters for superhydrophobicity of polymer surfaces fabricated by precision tooling machines [J].
Chu, Donghui ;
Nemoto, Akihiro ;
Ito, Hiroshi .
MICROSYSTEM TECHNOLOGIES-MICRO-AND NANOSYSTEMS-INFORMATION STORAGE AND PROCESSING SYSTEMS, 2014, 20 (02) :193-200
[5]   Superhydrophobic Nanocomposite Surface Topography and Ice Adhesion [J].
Davis, Alexander ;
Yeong, Yong Han ;
Steele, Adam ;
Bayer, Ilker S. ;
Loth, Eric .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (12) :9272-9279
[6]   Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating [J].
Deng, Xu ;
Mammen, Lena ;
Butt, Hans-Juergen ;
Vollmer, Doris .
SCIENCE, 2012, 335 (6064) :67-70
[7]   Wettability adjustment of PVDF surfaces by combining radiation-induced grafting of (2,3,4,5,6)-pentafluorostyrene and subsequent chemoselective "click-type" reaction [J].
Dumas, Ludovic ;
Fleury, Etienne ;
Portinha, Daniel .
POLYMER, 2014, 55 (11) :2628-2634
[8]   Wear-resistant rose petal-effect surfaces with superhydrophobicity and high droplet adhesion using hydrophobic and hydrophilic nanoparticles [J].
Ebert, Daniel ;
Bhushan, Bharat .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 384 :182-188
[9]  
Francisco R. D., 2014, ACS APPL MATER INTER, V6, P18998
[10]   Corrosion Resistance and Durability of Superhydrophobic Surface Formed on Magnesium Alloy Coated with Nanostructured Cerium Oxide Film and Fluoroalkylsilane Molecules in Corrosive NaCl Aqueous Solution [J].
Ishizaki, Takahiro ;
Masuda, Yoshitake ;
Sakamoto, Michiru .
LANGMUIR, 2011, 27 (08) :4780-4788