The morphological, electrical resistivity (ER), and electromagnetic interference (EMI) shielding effectiveness (SE) properties of poly(propylene) (PP), polystyrene (PS), PP/PS, and PP/PS/styrene-butadiene-styrene (SBS) blends filled with 10 vol.-% high structure carbon black (CB) were studied. For the CB/PP/PS blends, TEM and SEM observations indicated that CB is preferentially localized in the PS phase. ER and EMI SE of the CB/PP/PS and CB/PP/PS/SBS blends were bounded between those of the PS composite (lower bound) and the PP composite (upper bound). In the PP/PS volume ratio ranging from (75/25) to (25/75), ER and EMI SE of the CB-filled blends were independent of the PP/PS volume ratio. The EMI SE obtained by the 2 mm thick plates made of 10 vol.-% CB-filled (100/0)-(10/90) PP/PS blends are adequate for computers shielding applications.