Current characterization methods for cellulose nanomaterials

被引：783

作者：

Foster, E. Johan ^{[1
]}

Moon, Robert J. ^{[2
]}

Agarwal, Umesh P. ^{[2
]}

Bortner, Michael J. ^{[3
]}

Bras, Julien ^{[4
]}

Camarero-Espinosa, Sandra ^{[5
]}

Chan, Kathleen J. ^{[3
]}

Clift, Martin J. D. ^{[6
]}

Cranston, Emily D. ^{[7
]}

Eichhorn, Stephen J. ^{[8
]}

Fox, Douglas M. ^{[9
]}

Hamad, Wadood Y. ^{[10
]}

Heux, Laurent ^{[11
]}

Jean, Bruno ^{[11
]}

Korey, Matthew ^{[12
]}

Nieh, World ^{[13
]}

Ong, Kimberly J. ^{[14
]}

Reid, Michael S. ^{[7
]}

Renneckar, Scott ^{[15
]}

Roberts, Rose ^{[1
]}

Shatkin, Jo Anne ^{[14
]}

Simonsen, John ^{[16
]}

Stinson-Bagby, Kelly ^{[1
]}

Wanasekara, Nandula ^{[17
]}

Youngblood, Jeff ^{[12
]}

机构：

[1] Virginia Tech, Dept Mat Sci & Engn, 445 Old Turner St,203 Holden Hall, Blacksburg, VA 24061 USA

[2] US Forest Serv, Forest Prod Lab, 1 Gifford Pinchot Dr, Madison, WI 53726 USA

[3] Virginia Tech, Dept Chem Engn, 245 Goodwin Hall,635 Prices Fork Rd, Blacksburg, VA 24061 USA

[4] Univ Grenoble Alpes, CNRS, Agefpi, Lab Pulp & Paper Sci & Graph Arts LGP2, F-38000 Grenoble, France

[5] Maastricht Univ, MERLN Inst Technol Inspired Regenerat Med, Complex Tissue Regenerat Dept, Maastricht, Netherlands

[6] Swansea Univ, Sch Med, Ctr NanoHlth, In Vitro Toxicol Grp,Inst Life Sci, Swansea SA2 8PP, W Glam, Wales

[7] McMaster Univ, Dept Chem Engn, Hamilton, ON L8S 4L7, Canada

[8] Univ Bristol, Bristol Composites Inst ACCIS, Univ Walk, Bristol BS8 1TR, Avon, England

[9] Amer Univ, Dept Chem, Washington, DC 20016 USA

[10] FPInnovations, 2665 East Mall, Vancouver, BC V6T 1Z4, Canada

[11] Univ Grenoble Alpes, CNRS, CERMAV, F-38000 Grenoble, France

[12] Purdue Univ, Sch Mat Engn, W Lafayette, IN 47907 USA

[13] USDA Forest Serv Headquarters, R&D Deputy Area, 14th St SW, Washington, DC 20150 USA

[14] Vireo Advisors, Boston, MA 02205 USA

[15] Univ British Columbia, Dept Wood Sci, 2424 Main Mall, Vancouver, BC V6T 1Z4, Canada

[16] Oregon State Univ, Dept Forestry, Corvallis, OR 97331 USA

[17] Univ Exeter, Coll Engn Maths & Phys Sci, Harrison Bldg,North Pk Rd, Exeter, Devon, England

来源：

CHEMICAL SOCIETY REVIEWS | 2018年 / 47卷 / 08期

关键词：

TEMPO-MEDIATED OXIDATION; BIOMIMETIC MINERALIZATION SYNTHESIS; TRANSMISSION ELECTRON-MICROSCOPY; CURRENT INTERNATIONAL RESEARCH; QUARTZ-CRYSTAL MICROBALANCE; SULFURIC-ACID HYDROLYSIS; FT-RAMAN SPECTROSCOPY; CHIRAL NEMATIC PHASE; NANOCRYSTALLINE CELLULOSE; MICROFIBRILLATED CELLULOSE;

D O I：

10.1039/c6cs00895j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new family of materials comprised of cellulose, cellulose nanomaterials (CNMs), having properties and functionalities distinct from molecular cellulose and wood pulp, is being developed for applications that were once thought impossible for cellulosic materials. Commercialization, paralleled by research in this field, is fueled by the unique combination of characteristics, such as high on-axis stiffness, sustainability, scalability, and mechanical reinforcement of a wide variety of materials, leading to their utility across a broad spectrum of highperformance material applications. However, with this exponential growth in interest/ activity, the development of measurement protocols necessary for consistent, reliable and accurate materials characterization has been outpaced. These protocols, developed in the broader research community, are critical for the advancement in understanding, process optimization, and utilization of CNMs in materials development. This review establishes detailed best practices, methods and techniques for characterizing CNM particle morphology, surface chemistry, surface charge, purity, crystallinity, rheological properties, mechanical properties, and toxicity for two distinct forms of CNMs: cellulose nanocrystals and cellulose nanofibrils.

引用

页码：2609 / 2679

页数：71

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