Hydrogen desorption properties of MgH2 catalysed with NaNH2

被引：13
|
作者：
Milosevic, Sanja [1 ]
Milanovic, Igor [1 ]
Mamula, Bojana Paskas [1 ]
Dukic, Andelka [1 ]
Rajnovic, Dragan [3 ]
Pasquini, Luca [2 ]
Novakovic, Jasmina Grbovic [1 ]
机构：
[1] Univ Belgrade, Vinca Inst Nucl Sci, Belgrade 11000, Serbia
[2] Univ Bologna, Dept Phys & Astron, I-40127 Bologna, Italy
[3] Univ Novi Sad, Fac Tech Sci, Novi Sad 21000, Serbia
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2013年 / 38卷 / 27期
关键词：
MgH2; NaNH2; catalyst; Mechanical milling; Cycling; Hydrogen storage; STORAGE PROPERTIES; HYDRIDE; LI;
D O I：
10.1016/j.ijhydene.2013.06.083
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
To improve hydrogen desorption properties of MgH2, mechanical milling of MgH2 with low concentration (2 and 5%) of NaNH2 has been performed. Pre-milling of MgH2 for 10 h has been done and then six samples have been synthesised with different milling times from 15 to 60 min. Microstructural characterisation has been performed using X-ray diffraction (XRD), scanning electron microscopy (SEM) and laser scattering measurements (PSD), and correlated to desorption properties examined using Differential Scanning Calorimetry (DSC) and Hydrogen Sorption Analyser (HSA). Thermal analysis shows that desorption temperatures are shifted towards lower values. It also highlights the significance of milling time and additive concentration on desorption behaviour. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：12223 / 12229
页数：7
相关论文
共 50 条
  • [41] YCxFy nanosheets-supported Ni nanoparticles as a high-efficient catalyst for hydrogen desorption of MgH2
    Peng, Cong
    Zhang, Qingan
    NANO RESEARCH, 2023, 16 (08) : 10938 - 10945
  • [42] Hydrogen sorption kinetics of MgH2 catalyzed with titanium compounds
    Ma, Lai-Peng
    Wang, Ping
    Cheng, Hui-Ming
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (07) : 3046 - 3050
  • [43] Hydrogen desorption mechanism of 2NaBH4 + MgH2 composite prepared by high-energy ball milling
    Garroni, S.
    Pistidda, C.
    Brunelli, M.
    Vaughan, G. B. M.
    Surinach, S.
    Baro, M. D.
    SCRIPTA MATERIALIA, 2009, 60 (12) : 1129 - 1132
  • [44] Effects of CNTs on the hydrogen storage properties of MgH2 and MgH2-BCC composite
    Ranjbar, A.
    Ismail, M.
    Guo, Z. P.
    Yu, X. B.
    Liu, H. K.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (15) : 7821 - 7826
  • [45] Experimental and first principle studies on hydrogen desorption behavior of graphene nanofibre catalyzed MgH2
    Singh, Milind K.
    Bhatnagar, Ashish
    Pandey, Sunita K.
    Mishra, P. C.
    Srivastava, O. N.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (02) : 960 - 968
  • [46] Improved Hydrogen Desorption Kinetics of MgH2 Nanoparticles by using TiC Nanocatalyst
    Niaz, N. A.
    Hussain, S. T.
    Nasir, S.
    Ahmad, I.
    ADVANCED MATERIALS XII, 2012, 510-511 : 371 - +
  • [47] Hydrogen desorption kinetics of MgH2 synthesized from modified waste magnesium
    Figen, Aysel Kanturk
    Coskuner, Bilge
    Piskin, Sabriye
    MATERIALS SCIENCE-POLAND, 2014, 32 (03): : 385 - 390
  • [48] Hydrogen absorption and desorption kinetics of MgH2 catalyzed by MoS2 and MoO2
    Jia, Yanhong
    Han, Shumin
    Zhang, Wei
    Zhao, Xin
    Sun, Pengfei
    Liu, Yanqing
    Shi, He
    Wang, Jiasheng
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (05) : 2352 - 2356
  • [49] Hydrogen storage properties of MgH2 mechanically milled with α and β SiC
    Kurko, Sandra
    Raskovic, Zeljka
    Novakovic, Nikola
    Mamula, Bojana Paskas
    Jovanovic, Zoran
    Bascarevic, Zvezdana
    Nouakovic, Jasmina Grbovie
    Matovic, Ljiljana
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (01) : 549 - 554
  • [50] New synthetic procedure for NaNH2(BH3)2 and evaluation of its hydrogen storage properties
    Weidong Chen
    Zhenguo Huang
    Guotao Wu
    Ping Chen
    Science China Chemistry, 2015, 58 : 169 - 173
12345