g-Engineering in Hybrid Rotaxanes To Create AB and AB2 Electron Spin Systems: EPR Spectroscopic Studies of Weak Interactions between Dissimilar Electron Spin Qubits

被引：33

作者：

Fernandez, Antonio ^{[1
]}

Pineda, Eufemio Moreno ^{[1
]}

Muryn, Christopher A. ^{[1
]}

Sproules, Stephen ^{[1
]}

Moro, Fabrizio ^{[1
]}

Timco, Grigore A. ^{[1
]}

McInnes, Eric J. L. ^{[1
]}

Winpenny, Richard E. P. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 37期

基金：

英国工程与自然科学研究理事会;

关键词：

EPR spectroscopy; heterometallic complexes; magnetic properties; quantum computing; rotaxanes; ORGANIC-INORGANIC ROTAXANES; HETEROMETALLIC RINGS; COMPLEXES; WHEELS;

D O I：

10.1002/anie.201504487

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hybrid [2] rotaxanes and pseudorotaxanes are reported where the magnetic interaction between dissimilar spins is controlled to create AB and AB(2) electron spin systems, allowing independent control of weakly interacting S-1/2 centers.

引用

页码：10858 / 10861

页数：4

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