Telechelic Polymers by Visible-Light-Induced Radical Coupling

被引：33

作者：

Iskin, Birol ^{[1
]}

Yilmaz, Gorkem ^{[1
]}

Yagci, Yusuf ^{[1
,2
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2013年 / 214卷 / 01期

关键词：

ATRP; managanese decacarbonyl; radical coupling; telechelic polymers; visible light; IN-SITU SYNTHESIS; BLOCK-COPOLYMERS; POLY(METHYL ACRYLATE); MANGANESE CARBONYL; ELECTRON-TRANSFER; CLICK CHEMISTRY; CROSS-LINKING; POLYMERIZATION; NANOCOMPOSITES; COMBINATION;

D O I：

10.1002/macp.201200491

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A simple and efficient method to prepare telechelics by visible-light-induced radical coupling is presented. Irradiation of the toluene solutions of bromo-terminated polystyrenes prepared by atom transfer radical polymerization (ATRP) in the presence of an ester functional ATRP initiator and dimanganese decacarbonyl (Mn2(CO)10) at ? = 400500 nm leads to the formation telechelic polymers through radicalradical coupling. Adaptability of the process for the preparation of mono- and bifunctional telechelics is demonstrated under variety of conditions of ATRP and coupling steps.

引用

页码：94 / 98

页数：5

共 50 条

[21] Visible-Light-Induced Organocatalytic Borylation of Aryl Chlorides
Zhang, Li
Jiao, Lei
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (23) : 9124 - 9128
[22] Rhenium Complexes with Visible-Light-Induced Anticancer Activity
Kastl, Anja
Dieckmann, Sandra
Waehler, Kathrin
Voelker, Timo
Kastl, Lena
Merkel, Anna Lena
Vultur, Adina
Shannan, Batool
Harms, Klaus
Ocker, Matthias
Parak, Wolfgang J.
Herlyn, Meenhard
Meggers, Eric
CHEMMEDCHEM, 2013, 8 (06) : 924 - 927
[23] Visible-Light-Induced Bromination of α-Diazo Compounds with Bromoform
Zhang, Xin
Lin, Junyue
Liu, Miao-Chang
Zhou, Yun-Bing
Wu, Hua-Yue
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (04)
[24] Visible-Light-Induced Catalytic Selective Halogenation with Photocatalyst
Luu, Truong Giang
Jung, Yongju
Kim, Hee-Kwon
MOLECULES, 2021, 26 (23):
[25] Unexpected Visible-Light-Induced Free Radical Photopolymerization at Low Light Intensity and High Viscosity Using a Titanocene Photoinitiator
Kitano, Hajime
Ramachandran, Karthik
Bowden, Ned B.
Scranton, Alec B.
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 128 (01) : 611 - 618
[26] Visible-Light-Induced Atom-Transfer-Radical Polymerization with a ppm-Level Iron Catalyst
Bian, Chao
Zhou, Yin-Ning
Guo, Jun-Kang
Luo, Zheng-Hong
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2017, 56 (17) : 4949 - 4956
[27] Reactivity and Mechanistic Insight into Visible-Light-Induced Aerobic Cross-Dehydrogenative Coupling Reaction by Organophotocatalysts
Liu, Qiang
Li, Ya-Nan
Zhang, Hui-Hui
Chen, Bin
Tung, Chen-Ho
Wu, Li-Zhu
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (02) : 620 - 627
[28] A Versatile, Fast, and Efficient Method of Visible-Light-Induced Surface Grafting Polymerization
Xiong, Xinhong
Liu, Wei
Luan, Yafei
Du, Jun
Wu, Zhaoqiang
Chen, Hong
LANGMUIR, 2014, 30 (19) : 5474 - 5480
[29] Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans
Lin, Run
Sun, Hongnan
Yang, Chao
Yang, Youdong
Zhao, Xinxin
Xia, Wujiong
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2015, 11 : 1 - 6
[30] Metal Sulfide Photocatalysis: Visible-Light-Induced Organic Transformations
Hao, Huimin
Lang, Xianjun
CHEMCATCHEM, 2019, 11 (05) : 1378 - 1393

← 1 2 3 4 5 →