Kinetics of oxidation of primary alcohols by N-chloronicotinamide in aqueous acetic acid medium

被引：0

作者：

Ramkumar, B ^{[1
]}

机构：

[1] Saranathan Coll Engn, Dept Chem, Tiruchirappalli 620012, India

来源：

OXIDATION COMMUNICATIONS | 2001年 / 24卷 / 04期

关键词：

oxidation; primary alcohols; N-chloronicotinamide;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of some primary alcohols by N-chloronicotinamide (NCN) has been studied in 90% (v/v) acetic acid-water mixture. The reactions exhibit first order dependence in [NCN], [H+] and [Cl-]. A small increase in rate is observed in [alcohol]. Addition of the reaction product, nicotinamide, does not affect the rate. A suitable mechanism has been proposed.

引用

页码：554 / 557

页数：4

共 8 条

[1] OXIDATIONS AND DEHYDROGENATIONS WITH N-BROMOSUCCINIMIDE AND RELATED N-HALOMIDES [J].

FILLER, R .

CHEMICAL REVIEWS, 1963, 63 (01) :21-+

[2]

JAYARAMAN PS, 1982, P IND ACAD SCI CHEM, V91, P434

[3]

KUSELAN P, 1982, INDIAN J CHEM B, V21, P1095

[4]

RANGADURAI A, 1982, INDIAN J CHEM B, V21, P42

[5]

SENEHI R, 1987, INDIAN J CHEM A, V26, P399

[6] OXIDATION OF ALCOHOLS BY N-CHLOROSUCCINIMIDE - KINETIC STUDY [J].

SRINIVASAN, NS ;

VENKATASUBRAMANIAN, N .

TETRAHEDRON, 1974, 30 (03) :419-425

[7]

Vivekanandan K, 1999, J INDIAN CHEM SOC, V76, P198

[8]

Vivekanandan K, 1996, INDIAN J CHEM B, V35, P1117

← 1 →