Anionic polymerization of (meth)acrylic monomers:: anionic polymerization of tert-butyl methacrylate in toluene

被引:0
|
作者
Zune, C [1 ]
Dubois, P [1 ]
Jérôme, R [1 ]
机构
[1] Univ Liege, CERM, B-4000 Liege, Belgium
关键词
anionic polymerization; apolar solvent; (meth)acrylate;
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The anionic polymerization of tBMA initiated by an organolithium compound in toluene at low temperature (-78 degrees C and 0 degrees C) has been revisited. Under these experimental conditions, no 'livingness' is reported, consistently with formation of an important fraction of oligomers (M-n= 650). (C) 1999 Society of Chemical Industry.
引用
收藏
页码:565 / 570
页数:6
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