CATALYTIC ACTIVITY OF ELECTRODE MATERIALS BASED ON POLYPYRROLE, MULTI-WALL CARBON NANOTUBES AND COBALT PHTHALOCYANINE FOR THE ELECTROOXIDATION OF GLUTATHIONE AND L-CYSTEINE

被引:0
作者
Porras Gutierrez, Ana [1 ,2 ,3 ,4 ,5 ]
Rangel Argote, Magdalena [5 ]
Griveau, Sophie [1 ,2 ,3 ,4 ]
Zagal, Jose H. [6 ]
Gutierrez Granados, Silvia [5 ]
Alatorre Ordas, Alejandro [5 ]
Bedioui, Fethi [1 ,2 ,3 ,4 ]
机构
[1] Chim Paris Tech, Unite Pharmacol Chim & Genet & Imagerie UPCGI, F-75005 Paris, France
[2] CNRS, UMR 8151, F-75005 Paris, France
[3] Univ Paris 05, F-75006 Paris, France
[4] INSERM, U1022, F-75005 Paris, France
[5] Univ Guanajuato, Dept Quim, Div Ciencias Nat & Exactas, Guanajuato, Mexico
[6] Univ Santiago Chile, Fac Quim & Biol, Dept Quim Mat, Santiago 9170022, Chile
来源
JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2012年 / 57卷 / 03期
关键词
Electrocatalysis; thiols; modified electrodes; carbon nanotubes; ELECTROCATALYTIC ACTIVITY; GRAPHITE ELECTRODE; TETRASULFONATED PHTHALOCYANINE; TETRA-AMINOPHTHALOCYANINE; ELECTROCHEMICAL REACTIONS; REDUCED GLUTATHIONE; MOLECULAR MATERIALS; HAMMETT PARAMETERS; BASAL-PLANE; OXIDATION;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrodes prepared from overoxidized pyrrole, multi-walled carbon nanotubes (MWCNT) and cobalt phthalocyanine (CoPc) exhibit a clear catalytic activity for the electrooxidation of L-cysteine and reduced gluthatione. The electrodes are more stable than the ones modified by simple adsorption of CoPc and/or MWCNT. Therefore, these materials offer a good alternative for the development of electrocatalytic applications and thiols detection in biological interest.
引用
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页码:1244 / 1247
页数:4
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