Synthesis, Crystal Structure and Properties of the Nickel(II) 4′-(p-methoxylphenyl)-2,2′:6′,2"-terpyridine Complex

被引：13

作者：

Fu Wei-Wei ^{[1
]}

Kuang Dai-Zhi ^{[1
]}

Zhang Fu-Xing ^{[1
]}

Liu Yang ^{[1
]}

Li Wei ^{[1
]}

Kuang Yun-Fei ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat Gerneral Inst High, Hengyang 421008, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 03期

关键词：

nickel(II) complex; terpyridine; fluerescence; cyclic voltammetry; NI; TERPYRIDINE;

D O I：

10.3969/j.issn.1001-4861.2013.00.099

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex has been synthesized with 4'-(p-methoxylphenyl)-2,2':6',2 ''-terpyridine (meophtpy) and zinc sulfate heptahydrate (NiSO4 center dot 7H(2)O), sodium perchlorate (NaClO4) with solvothermal method and characterized by IR, UV and X-ray diffraction. It crystallizes in monoclinic space group P2(1)/c. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from two terpyridine molecules, forming six-coordinated octahedral coordination geometry. There are three abosrpsion peaks 235.5, 278.5 and 342 nm which are the typical absorption spectrum of terpyridine complexes. The fluerescence are peaked at 396 nm. Following a cyclic voltammetry measurement a typical reduction peak of Ni2+ at -0.82 V was found. CCDC: 899537.

引用

页码：654 / 658

页数：5

共 21 条

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