Degradation of aniline in aqueous solution by dielectric barrier discharge plasma: Mechanism and degradation pathways

被引：60
|
作者：
Sang, Wenjiao [1 ]
Cui, Jiaqi [1 ]
Feng, Yijie [1 ]
Mei, Longjie [1 ]
Zhang, Qian [1 ]
Li, Dong [1 ]
Zhang, Wanjun [2 ]
机构：
[1] Wuhan Univ Technol, Sch Civil Engn & Architecture, Wuhan 430070, Hubei, Peoples R China
[2] Cent & Southern China Municipal Engn Design & Res, Wuhan 430010, Hubei, Peoples R China
来源：
CHEMOSPHERE | 2019年 / 223卷
关键词：
Dielectric barrier discharge (DBD); Aniline; Degradation efficiency; Hydroxyl radical; Degradation pathways; HIGH-VOLTAGE DISCHARGE; WASTE-WATER; NONTHERMAL PLASMA; ACTIVATED CARBON; METHYLENE-BLUE; DBD REACTOR; AZO-DYE; REMOVAL; 4-CHLOROPHENOL; MINERALIZATION;
D O I：
10.1016/j.chemosphere.2019.02.029
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The degradation of aniline solution using the dielectric barrier discharge (DBD) plasma was studied in this paper. The results indicated that the initial concentration of aniline, applied voltage and initial pH value affected the removal efficiency of aniline significantly. After 12 min with DBD plasma treatment, 90.2% removal efficiency was achieved at aniline concentration of 100 mg L-1 with an applied voltage of 3.0 kV and pH 8.43. The removal efficiency decreased with the presence of radical scavengers, indicating that hydroxyl radical plays a key role in the degradation process. The removal efficiency increased obviously when Fe2+ was added. Additionally, the intermediate products generated in the degradation process of aniline were analyzed by some analytical techniques, including total organic carbon analysis, ultraviolet-visible spectroscopy, Fourier Transform Infrared spectroscopy, Gas Chromatography-Mass Spectrometer, etc. The results showed that the degradation of aniline was mainly due to the strong oxidizing capacity of hydroxyl radical produced by the DBD plasma system. Based on the intermediate products identified in the study, the possible degradation mechanism and pathways were proposed. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码：416 / 424
页数：9
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