Incorporation of metal nanoparticles in photopolymerized organic conducting polymers: A mechanistic insight

被引：109

作者：

Breimer, MA ^{[1
]}

Yevgeny, G ^{[1
]}

Sy, S ^{[1
]}

Sadik, OA ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

NANO LETTERS | 2001年 / 1卷 / 06期

关键词：

D O I：

10.1021/nl015528w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrically conducting polymers were prepared through a systematic photopolymerization of polypyrrole with the incorporation of Group 1B metal particles. The structural and morphological properties of incorporated metal nanoparticles were examined with respect to the role of the metals ions, nature of substrates, exposure time, and monomer counterion ratios, Elemental analysis confirmed the identities of the particles with sizes on the order of hundreds of nanometers in diameter. A mechanism is proposed for the formation of metal nanostructure during photopolymerization.

引用

页码：305 / 308

页数：4

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