2-Phospha[3]ferrocenophanes with Planar Chirality: Synthesis and Use in Enantioselective Organocatalytic [3+2] Cyclizations

被引：245

作者：

Voituriez, Arnaud ^{[1
]}

Panossian, Armen ^{[1
]}

Fleury-Bregeot, Nicolas ^{[1
]}

Retailleau, Pascal ^{[1
]}

Marinetti, Angela ^{[1
]}

机构：

[1] CNRS, Inst Chim Subst Nat, UPR 2301, F-91198 Gif Sur Yvette, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 43期

关键词：

D O I：

10.1021/ja806060a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Planar chiral phosphines displaying a new ferrocenophane scaffold have been prepared via a stereoselective approach. The P-cyclohexyl substituted phosphine affords high levels of asymmetric induction in the organocatalytic [3 + 2] annulation reaction between allenes and electron-poor olefins.

引用

页码：14030 / +

页数：3

共 32 条

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