Synthesis, crystal structure and properties of a new strontium cadmium diborate

被引：4
|
作者：
Cao, Jian [1 ,2 ]
Gao, Junyu [1 ,2 ]
Pan, Shilie [1 ]
Yu, Hongwei [1 ,2 ]
Zhao, Wenwu [1 ,2 ]
Yang, Zhihua [1 ]
机构：
[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2012年 / 392卷
基金：
中国国家自然科学基金;
关键词：
SrCdB2O5; Crystal structure; Diborate; X-ray diffraction; OPTICAL-PROPERTIES; GENERATION; GROWTH; BORATE; POLAR;
D O I：
10.1016/j.ica.2012.03.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound, SrCdB2O5, has been grown by the high temperature solution method from the SrO-Cd-B2O3 system for the first time. It crystallizes in the orthorhombic system, space group Pbca with unit-cell parameters a = 12.010(4) angstrom, b = 5.795(2) angstrom, c = 12.677(4) angstrom, Z = 8, volume = 882.4(5) angstrom(3). Its structure is solved by the direct methods and refined to R-1 = 0.0256 and wR(2) = 0.0727. The new structure contains an infinite three-dimensional matrix that is built from B2O5 units and CdO6 and SrO9 polyhedra. Spectrum properties, thermal analysis and theoretical calculations on electronic structure of SrCdB2O5 were reported. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码：459 / 464
页数：6
相关论文
共 50 条
  • [31] Synthesis, crystal structure and photochromic properties of a new unsymmetrical diarylethene
    Fan, Congbin
    Cui, Shiqiang
    Pu, Shouzhi
    Huang, Qianli
    Liu, Gang
    JOURNAL OF CHEMICAL RESEARCH, 2013, (09) : 574 - 578
  • [32] Synthesis, crystal structure and properties of the new superconductors TaRuB and NbOsB
    Zheng, Qiang
    Gumeniuk, Roman
    Rosner, Helge
    Schnelle, Walter
    Prots, Yurii
    Burkhardt, Ulrich
    Grin, Yuri
    Leithe-Jasper, Andreas
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2015, 27 (41)
  • [33] Synthesis and Crystal Structure of Ammonium, Strontium Hexacyanoferrate(II) Dihydrate
    L. Medina Córdoba
    J. A. Morán
    S. Santos
    O. E. Piro
    M. I. Gómez
    Journal of Chemical Crystallography, 2011, 41
  • [34] Synthesis, Crystal Structure and Properties of the Strontium Vanadate Fluoride Sr5(VO4)3F
    Zhang, Fangyuan
    Zhang, Fangfang
    Jing, Qun
    Pan, Shilie
    Yang, Zhihua
    Jia, Dianzeng
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (07): : 1211 - 1215
  • [35] Synthesis and Crystal Structure of Ammonium, Strontium Hexacyanoferrate(II) Dihydrate
    Medina Cordoba, L.
    Moran, J. A.
    Santos, S., Jr.
    Piro, O. E.
    Gomez, M. I.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (09) : 1280 - 1284
  • [36] Synthesis, Crystal Structure and Magnetic Properties of a new Hydroxylammonium Fluoroferrate
    Dojer, Brina
    Kristl, Matjaz
    Jaglicic, Zvonko
    Golobic, Amalija
    Kasunic, Marta
    Drofenik, Mihael
    ACTA CHIMICA SLOVENICA, 2012, 59 (04) : 789 - 794
  • [37] Synthesis and crystal structure of a noncentrosymmetric form of potassium strontium monovanadate KSrVO4
    Azrour, M
    El Ammari, L
    Le Fur, Y
    Elouadi, B
    MATERIALS RESEARCH BULLETIN, 2000, 35 (02) : 263 - 270
  • [38] Synthesis, crystal structure, spectroscopic properties, and electronic structure of a new borate, EuCd3(AlO)3(BO3)4
    Chen, Xuean
    Zhao, Liang
    Chang, Xinan
    Xiao, Weiqiang
    MATERIALS CHEMISTRY AND PHYSICS, 2019, 237
  • [39] Synthesis, crystal structure and optical properties of the new lead fluoride borate-Pb2BO3F
    Zhao, Wenwu
    Pan, Shilie
    Han, Jian
    Yao, Jiyong
    Yang, Yun
    Li, Junjie
    Zhang, Min
    Zhang, Lian Han
    Hang, Yin
    JOURNAL OF SOLID STATE CHEMISTRY, 2011, 184 (11) : 2849 - 2853
  • [40] Use of Polyazaheterocycles in the Assembly of New Cadmium Sulfate Frameworks: Synthesis, Structure, and Properties
    Paul, Avijit Kumar
    Sanyal, Udishnu
    Natarajan, Srinivasan
    CRYSTAL GROWTH & DESIGN, 2010, 10 (09) : 4161 - 4175
12345