Organic-inorganic hybrid complexes based on a Keggin-type polyoxoanion

被引：4
|
作者：
Lan, Qing [1 ]
Lu, Ying [1 ]
Li, Yang-Guang [1 ]
Tan, Hua-Qiao [1 ]
Liu, Ding [1 ]
Wang, En-Bo [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2012年 / 37卷 / 05期
基金：
中国国家自然科学基金;
关键词：
3D ARCHITECTURES; POLYOXOMETALATE; FRAMEWORK; CLUSTERS; COPPER; CATALYST; ALPHA;
D O I：
10.1007/s11243-012-9608-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two organic-inorganic hybrid complexes based on a Keggin-type polyoxoanion, namely [Ni-2(H2O)(2)(bipy)(4)(Hbipy)][AlW12O40]center dot 7H(2)O 1 and [Ni2Cl2(bipy)(3)(Hbipy)(2)][SiW12O40]center dot 2.5H(2)O 2 (bipy = 4,4'-bipy), have been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction. Complexes 1 and 2 possess similar 2D layer structures, constructed from 1D zigzag chains {Ni(bipy)} (n) (2n+) and alternatively arranged Keggin anion and bipy linkers. Photocatalytic investigations indicate that both 1 and 2 exhibit photocatalytic activity for the degradation of Rhodamine B.
引用
收藏
页码：445 / 451
页数：7
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