Recent advances in chemistry of high-spin nitrenes

被引：10

作者：

Chapyshev, Sergei, V ^{[1
]}

Korchagin, Denis, V ^{[1
]}

Misochko, Evgenii Ya ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Akad Sernenova 1, Chernogolovka 142432, Moscow Region, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2021年 / 90卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

MAGNETIC-ANISOTROPY PARAMETERS; FIELD SPLITTING PARAMETERS; LOW-TEMPERATURE RADIOLYSIS; AB-INITIO MO; GROUND-STATE; MATRIX-ISOLATION; SPECTROSCOPIC CHARACTERIZATION; PHOTOCHEMICAL GENERATION; QUINTET DINITRENES; EPR SPECTROSCOPY;

D O I：

10.1070/RCR4965

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Experimental and theoretical studies on aromatic nitrenes bearing from three to six unpaired electrons and having quartet, quintet, sextet or septet ground spin states, published in the last 15 years are analyzed. A comparative analysis of the magnetic properties of high-spin nitrenes and all other known high-spin organic molecules is performed. Promising areas of practical application of high-spin nitrenes as molecular magnets and as qubits and qudits for quantum computations are discussed.

引用

收藏

页码：39 / 69

页数：31

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