In Situ Fabrication of PtCo Alloy Embedded in Nitrogen-Doped Graphene Nanopores as Synergistic Catalyst for Oxygen Reduction Reaction

被引:27
作者
Zhong, Xing [1 ]
Wang, Lei [1 ]
Zhou, Hu [1 ]
Qin, Yingying [1 ]
Xu, Wenlei [1 ]
Jiang, Yu [1 ]
Sun, Youyi [1 ]
Shi, Zheqi [1 ]
Zhuang, Guilin [1 ]
Li, Xiaonian [1 ]
Mei, Donghai [2 ]
Wang, Jian-Guo [1 ]
机构
[1] Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310032, Zhejiang, Peoples R China
[2] Pacific NW Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA
基金
中国国家自然科学基金;
关键词
POROUS GRAPHENE; RECENT PROGRESS; HYDROGEN STORAGE; DNA; NANOPARTICLES; PERFORMANCE; ELECTROCATALYSTS; TRANSLOCATION; MEMBRANE;
D O I
10.1002/admi.201500365
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In situ fabrication of a PtCo alloy etched and embedded in nitrogen-doped graphene nanopores (PtCo/NPG) serve as high-performing electrocatalysts for the oxygen reduction reaction (ORR). Density functional theory calculations indicate that the nanopores in NPG can not only stabilize PtCo nanoparticles but can also change the electronic structures of PtCo, thereby enhancing ORR performance. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页数:7
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