Multicomponent adsorption of butane, NO2 and SO2 on activated carbon

被引:14
|
作者
Ahnert, F [1 ]
Heschel, W
机构
[1] Delft Univ Technol, Thermal Power Engn Sect, NL-2628 CD Delft, Netherlands
[2] Freiberg Univ Min & Technol, Inst Energy Proc & Chem Engn, D-09596 Freiberg, Germany
关键词
D O I
10.1260/02636170260295542
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Dynamic adsorption experiments have been carried out with the help of an FT-help of an FT IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorptionhelp of an FT IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorptionhelp of an FT IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorptionhelp of an FT IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorption IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorption breakthrough curves were obtained for n-butane, SO2 and NO2 gases as well as for the reaction products NO, N2O and CO2. The adsorption of SO2 and NO2 on activated carbon was studied both during single- and co-adsorption experiments at 30 C. The activated carbon used exhibited a disadvantage towards NO2 adsorption in that it was partly converted to NO and immediately desorbed as NO. A further reaction to N2O could also be observed. The activated carbon was rapidly altered and lost a notable part of its loading capacity as a result of the presence of water and oxygen. During co-adsorption, SO2 reacted with NO2 (both as adsorbed species) and produced an additional amount of NO. An ash-tree spherical activated carbon with an extended surface area (1000 m(2)/g) was used in all experiments.
引用
收藏
页码:353 / 370
页数:18
相关论文
共 50 条
  • [1] To the multicomponent adsorption of NO2, SO2 and butane from air on activated carbon
    Heschel, Wolfgang
    Ahnert, Falk
    Chemische Technik (Leipzig), 1998, 50 (06): : 293 - 301
  • [2] Adsorption of SO2 and chlorobenzene on activated carbon
    Yangyang Guo
    Yuran Li
    Tingyu Zhu
    Meng Ye
    Xue Wang
    Adsorption, 2013, 19 : 1109 - 1116
  • [3] Adsorption of SO2 and chlorobenzene on activated carbon
    Guo, Yangyang
    Li, Yuran
    Zhu, Tingyu
    Ye, Meng
    Wang, Xue
    ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2013, 19 (06): : 1109 - 1116
  • [4] SO2 Adsorption on Activated Carbon.
    Koch, R.-K.
    Schenk, J.
    Luft- und Kaltetechnik Karlsruhe, 1984, 20 (03): : 157 - 159
  • [5] Research of Adsorption Dynamics for SO2 on Activated Carbon
    Su, Qing-qing
    Li, Liang
    Hu, Zhi-hua
    Luo, Yu-hong
    Gao, Ting
    Peng, Wei-dong
    Zhao, Xiao-rong
    INTERNATIONAL CONFERENCE ON WATER RESOURCE AND ENVIRONMENTAL PROTECTION WREP 2014, 2014, : 483 - 488
  • [6] Adsorption kinetics of SO2 on powder activated carbon
    Li, Bing
    Zhang, Qilong
    Ma, Chunyuan
    INTERNATIONAL CONFERENCE ON ENERGY ENGINEERING AND ENVIRONMENTAL PROTECTION (EEEP2017), 2018, 121
  • [7] Adsorption and desorption of SO2, NO and chlorobenzene on activated carbon
    Li, Yuran
    Guo, Yangyang
    Zhu, Tingyu
    Ding, Song
    JOURNAL OF ENVIRONMENTAL SCIENCES, 2016, 43 : 128 - 135
  • [8] Adsorption and desorption of SO2, NO and chlorobenzene on activated carbon
    Yuran Li
    Yangyang Guo
    Tingyu Zhu
    Song Ding
    Journal of Environmental Sciences , 2016, (05) : 128 - 135
  • [9] Adsorption equilibrium and kinetics of SO2 on activated carbon
    Li, Bing
    Jiang, Hai-Tao
    Zhang, Li-Qiang
    Wang, Zhi-Qiang
    Ma, Chun-Yuan
    Meitan Xuebao/Journal of the China Coal Society, 2012, 37 (10): : 1737 - 1742
  • [10] Investigation of SO2 and NO adsorption species on activated carbon and the mechanism of NO promotion effect on SO2
    Guo, Yangyang
    Li, Yuran
    Zhu, Tingyu
    Ye, Meng
    FUEL, 2015, 143 : 536 - 542