Product analysis of selective catalytic reduction of NO2 with C2H4 over H-ferrierite

被引：31

作者：

Nanba, T ^{[1
]}

Obuchi, A ^{[1
]}

Sugiura, Y ^{[1
]}

Kouno, C ^{[1
]}

Uchisawa, J ^{[1
]}

Kushiyama, S ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Inst Environm Management Technol, Tsukuba, Ibaraki 3058569, Japan

来源：

JOURNAL OF CATALYSIS | 2002年 / 211卷 / 01期

关键词：

selective catalytic reduction; H-ferrierite; NO2; product analysis; nitroethylene; HNCO; HCN; hydrolysis; NH3;

D O I：

10.1006/jcat.2002.3746

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction paths of the selective catalytic reduction of NO2 by C2H4 over H-ferrierite were investigated by identifying and measuring the reactivity of the by-products under various coexisting gas conditions. Nitroethylene (NE), HCN, and HNCO were detected as nitrogen-containing by-products. It was found that there were two reaction pathways for N-2 formation: the direct reaction between NE and NO2, and NE decomposition followed by the formation and hydrolysis of HNCO. The latter pathway led to the formation of NH3, which further reacted with NOx to form N-2. (C) 2002 Elsevier Science (USA).

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页码：53 / 63

页数：11

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