Tris(1,10-phenanthroline)copper(II) tricyanomethanide

被引：15

作者：

Potocnák, I

Pohlová, M

Wagner, C

Jäger, L

机构：

[1] Safarik Univ, Dept Inorgan Chem, Inst Chem, SK-04154 Kosice, Slovakia

[2] Univ Halle Wittenberg, Inst Inorgan Chem, D-06099 Halle An Der Saale, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷

关键词：

D O I：

10.1107/S1600536802017610

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of [Cu(C12H8N2)(3)][C(CN)(3)](2) is composed of discrete [Cu(phen)(3)](2+) cations (phen is 1,10-phenanthroline) and [C(CN)(3)](-) anions. The Cu-II atom is octahedrally coordinated by the three phen ligands. As a consequence of the Jahn-Teller effect, the two axial Cu-N bonds of 2.219 (3) and 2.238 (3) Angstrom are longer than the equatorial Cu-N bonds, which are in trans positions, paired in two couples of almost equal distance [2.066 (3)/2.050 (3) and 2.121 (3)/2.121 (3) Angstrom].

引用

页码：M595 / M596

页数：2

共 5 条

[1]

*CRYST IMP, 1999, DIAMOND REL 2 1 E

[2] Bis(2,2'-bipyridine-N,N')(tricyanomethanido-N)copper(II) tricyanomethanide [J].