Observation of Cu2+-H2 interactions in a fully desolvated sodalite-type metal-organic framework

被引：372

作者：

Dinca, Mircea

Han, Won Seok

Liu, Yun

Dailly, Anne

Brown, Craig M.

Long, Jeffrey R. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA

[3] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA

[4] GM Corp, Chem & Environm Sci Lab, Warren, MI 48090 USA

[5] Purdue Univ, Coll Engn, W Lafayette, IN 47907 USA

[6] Indiana Univ, Cyclotron Facil, Bloomington, IN 47408 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 09期

关键词：

copper; hydrogen; metal-organic frameworks; microporous materials; neutron diffraction;

D O I：

10.1002/anie.200604362

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Metal-H2 binding: A new tetrazolate-based metal-organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N blue, Cl green). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1419 / 1422

页数：4

共 24 条

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