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A study on thermal behavior of uncalcined Ca(H2PO4)2•.H2O and CaCO3 mixtures
被引:12
|作者:
Hsu, CK
[1
]
机构:
[1] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, Taipei, Taiwan
关键词:
uncalcined Ca(H2PO4)(2)center dot.H2O and CaCO3 mixtures;
DTA;
TG;
dehydration;
decomposition;
non-isothermal DTA kinetics;
D O I:
10.1016/S0040-6031(02)00096-5
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
Biphase composites of hydroxyapatite (HA) and P-tricalcium phosphate, (TCP) with various phase compositions have been obtained by controlling the molar ratio of Ca(HPO4).2H(2)O and CaCO3 at an appropriate value between 1.5 and 2.0. In this work, biphase composites of HA and beta-TCP with various phase compositions were prepared from the uncalcined Ca(H2PO4)(2).H2O and CaCO3 mixtures. The thermal properties of uncalcined raw materials were investigated using DTA/DSC/TG. The kinetic parameters of dehydration and decomposition for uncalcined Ca(H2PO4)(2).H2O/CaCO3 mixtures were also evaluated by non-isothermal differential thermal analysis (DTA) techniques. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码:157 / 161
页数:5
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