A study on thermal behavior of uncalcined Ca(H2PO4)2•.H2O and CaCO3 mixtures

被引:12
|
作者
Hsu, CK [1 ]
机构
[1] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, Taipei, Taiwan
关键词
uncalcined Ca(H2PO4)(2)center dot.H2O and CaCO3 mixtures; DTA; TG; dehydration; decomposition; non-isothermal DTA kinetics;
D O I
10.1016/S0040-6031(02)00096-5
中图分类号
O414.1 [热力学];
学科分类号
摘要
Biphase composites of hydroxyapatite (HA) and P-tricalcium phosphate, (TCP) with various phase compositions have been obtained by controlling the molar ratio of Ca(HPO4).2H(2)O and CaCO3 at an appropriate value between 1.5 and 2.0. In this work, biphase composites of HA and beta-TCP with various phase compositions were prepared from the uncalcined Ca(H2PO4)(2).H2O and CaCO3 mixtures. The thermal properties of uncalcined raw materials were investigated using DTA/DSC/TG. The kinetic parameters of dehydration and decomposition for uncalcined Ca(H2PO4)(2).H2O/CaCO3 mixtures were also evaluated by non-isothermal differential thermal analysis (DTA) techniques. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:157 / 161
页数:5
相关论文
共 50 条
  • [31] Synthesis, crystal structure, and magnetic properties of K4Mn3(HPO4)4(H2PO4)2
    Feng, Dawei
    Wang, Cheng
    Cheng, Wentai
    Li, Guobao
    Tian, Shujian
    Liao, Fuhui
    Xiong, Ming
    Lin, Jianhua
    SOLID STATE SCIENCES, 2009, 11 (04) : 845 - 851
  • [32] A kinetic study on oxidation of ferrous sulfide (FeS) in mixtures of CO2 and H2O
    Lv, Weizhi
    Yu, Dunxi
    Wu, Jianqun
    Yu, Xin
    Du, Yifan
    Yao, Hong
    Xu, Minghou
    PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2017, 36 (02) : 2173 - 2180
  • [33] Phase transition and thermal decomposition of [Cd(H2O)6](BF4)
    Mikuli, E
    Migdal-Mikuli, A
    Gajerski, R
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2002, 68 (03): : 861 - 864
  • [34] Synthesis, crystal structure and thermal study of the hybrid nickel sulfate: C6N2H16[Ni(H2O)6(SO4)2]•2H2O
    Ngopoh, F. A. I.
    Chaouchl, S.
    Lachkarl, M.
    da Silva, I.
    El Bali, B.
    1ST INTERNATIONAL ONLINE CONFERENCE ON NANOSCIENCE & NANOTECHNOLOGY (N@NO'2017), 2018, 984
  • [35] Synthesis and thermal decomposition of [Ni2(C4H4O6)2]•7H2O
    Dass, NN
    Sarmah, S
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1999, 58 (01): : 137 - 145
  • [36] Two Environmentally Friendly Energetic Compounds, [Mn(AZT)4(H2O)2](PA)2•4H2O and [Co(AZT)2(H2O)4](PA)2, Based on 3-Azido-1,2,4-triazole (AZT) and Picrate (PA)
    Wu, Bi-Dong
    Zhang, Jian-Guo
    Zhang, Tong-Lai
    Yang, Li
    Zhou, Zun-Ning
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (08) : 1261 - 1268
  • [37] Synthesis and Thermal Decomposition of [Ni2(C4H4O6)2]·7H2O
    N. N. Dass
    S. Sarmah
    Journal of Thermal Analysis and Calorimetry, 1999, 58 : 137 - 145
  • [38] Dehydration of blodite, Na2Mg(SO4)2(H2O)4, and leonite, K2Mg(SO4)2(H2O)4
    Balic-Zunic, Tonci
    Birkedal, Renie
    Katerinopoulou, Anna
    Comodi, Paola
    EUROPEAN JOURNAL OF MINERALOGY, 2016, 28 (01) : 33 - 42
  • [39] Na(H2O)[Mn(H2O)2(BP2O8)]: Crystal structure refinement
    Yakubovich, O. V.
    Steele, I.
    Dimitrova, O. V.
    CRYSTALLOGRAPHY REPORTS, 2009, 54 (01) : 13 - 18
  • [40] Chemical preparation, crystallographic characterization, vibrational study and thermal behavior of a new cyclotriphosphate CaNH4P3O9 • H2O
    Majdi, El Mehdi
    Tridane, Malika
    Zerraf, Soufiane
    Belaaouad, Said
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2022, 197 (11) : 1160 - 1169