A study of nitrobenzene hydrogenation over palladium/carbon catalysts

被引：80
作者：
Gelder, EA
Jackson, SD [1 ]
Lok, CM
机构：
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
[2] Synetix, Billingham TS23 1LB, Cleveland, England
来源：
CATALYSIS LETTERS | 2002年 / 84卷 / 3-4期
基金：
英国工程与自然科学研究理事会;
关键词：
palladium; nitrobenzene; hydrogenation; carbon; aniline; particle size effect;
D O I：
10.1023/A:1021432104496
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrogenation of nitrobenzene has been studied over three palladium/carbon catalysts using methanol and isopropanol as solvents. A solvent and palladium particle size effect have both been observed, with the nature of the particle size effect dependent upon the solvent. This may be related to a change in the rate-determining step.
引用
收藏
页码：205 / 208
页数：4
相关论文
共 12 条
  • [1] Study on silica supported Cu-Cr-Mo nitrobenzene hydrogenation catalysts
    Fang, XM
    Yao, SL
    Qing, Z
    Li, FY
    [J]. APPLIED CATALYSIS A-GENERAL, 1997, 161 (1-2) : 129 - 135
  • [2] Haber F., 1898, Z. Electrochem. Angew. Phys. Chem., V4, P506
  • [3] Höller V, 2000, CHEM ENG TECHNOL, V23, P251
  • [4] Jebarathinam NJ, 1998, STUD SURF SCI CATAL, V113, P1039
  • [5] KOCHETOVA LB, 2000, PETROL CHEM, V40, P371
  • [6] NITROBENZENE HYDROGENATION OVER ALUMINUM BORATE-SUPPORTED PLATINUM CATALYST
    LI, CP
    CHEN, YW
    WANG, WJ
    [J]. APPLIED CATALYSIS A-GENERAL, 1994, 119 (02) : 185 - 194
  • [7] HYDROGENATION OF NITROBENZENE OVER PALLADIUM-SILVER CATALYSTS
    METCALFE, A
    ROWDEN, MW
    [J]. JOURNAL OF CATALYSIS, 1971, 22 (01) : 30 - &
  • [8] Perez MCM, 1997, APPL CATAL A-GEN, V151, P461
  • [9] van Hardeveld R., 1972, ADV CATAL, V22, P75
  • [10] WEISSERMEL K, 1997, IND ORGANIC CHEM, P375
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