Novel environment-friendly yellow pigments based on praseodymium(III) tungstate

被引：26

作者：

Bae, Byungseo ^{[1
]}

Tamura, Shinji ^{[1
]}

Imanaka, Nobuhito ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan

来源：

CERAMICS INTERNATIONAL | 2017年 / 43卷 / 09期

关键词：

Inorganic yellow pigment; Environment-friendly; Trivalent cerium ion; Solid-state reaction method; LUMINESCENCE; PHOSPHORS; PR; SM;

D O I：

10.1016/j.ceramint.2017.02.103

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The novel environment-friendly inorganic yellow pigments, (Pr1-xCex)(2)W2O9+delta (0 <x <= 0.12) with the monoclinic structure, were synthesized and their color properties were investigated. The (Pr1-xCex)(2)W2O9+delta (0 < x <= 0.12) samples showed brilliant yellow color by doping trivalent Ce3+ into the Pr2W2O9 lattice due to the optical absorption in blue light region caused by the 4f -5d transition of Ce3+. According to the XPS and Rietveld analysis results, cerium ions in the crystal lattice have two different oxidation states of 3+ and 4+, in which the rate of each oxidation state is 58%:42%, and the Ce3+ and Ce4+ ions are preferentially occupied the PrO9 and the PrO8 polyhedral sites, respectively. Among the samples prepared, the (Pr0.90Ce0.10)(2)W2O9+delta pigment exhibited the most vivid yellow hue with high color durability for light and acid/base solutions.

引用

页码：7366 / 7368

页数：3

共 10 条

[1] Luminescence properties of tungstates and molybdates phosphors: Illustration on ALn(MO4)2 compounds (A = alikaline cation, Ln = lanthanides, M = W, Mo) [J].

Benoit, Glorieux ;

Veronique, Jubera ;

Arnaud, Apheceixborde ;

Alain, Garcia .

SOLID STATE SCIENCES, 2011, 13 (02) :460-467

[2] Luminescence Characteristics of Pr3+ Ion Doped CaTiO3 Nanopowder Phosphors Synthesized by Solvothermal Method [J].

Chung, Jong Won ;

Yang, Hyun Kyoung ;

Moon, Byung Kee ;

Choi, Byung Chun ;

Jeong, Jung Hyun ;

Kim, Jung Hwan .

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2011, 11 (07) :6208-6212

[3]

Faulkner E.B., 2009, High Performance Pigments, V2nd

[4] Three-dimensional visualization in powder diffraction [J].

Izumi, Fujio ;

Momma, Koichi .

APPLIED CRYSTALLOGRAPHY XX, 2007, 130 :15-20

[5] Inorganic yellow-red pigments without toxic metals [J].

Jansen, M ;

Letschert, HP .

NATURE, 2000, 404 (6781) :980-982

[6] Up/down conversion luminescence and charge compensation investigation of Ca0.5Y1-x(WO4)2:xLn3+ (Ln = Pr, Sm, Eu, Tb, Dy, Yb/Er) phosphors [J].

Mahalingam, Venkatakrishnan ;

Thirumalai, Jagannathan ;

Krishnan, Rajagopalan ;

Mantha, Srinivas .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2016, 152 :172-180

[7] Novel and environmentally friendly (Bi,Ca,Zn)VO4 yellow pigments [J].

Masui, Toshiyuki ;

Honda, Taihei ;

Wendusu ;

Imanaka, Nobuhito .

DYES AND PIGMENTS, 2013, 99 (03) :636-641

[8] VESTA:: a three-dimensional visualization system for electronic and structural analysis [J].

Momma, Koichi ;

Izumi, Fujio .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2008, 41 :653-658

[9] REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].

SHANNON, RD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767

[10] Dielectric properties of RE2W2O9 (RE = Pr, Sm-Gd) ceramics [J].

Urbanowicz, P. ;

Piatkowska, M. ;

Sawicki, B. ;

Gron, T. ;

Kukula, Z. ;

Tomaszewicz, E. .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2015, 35 (15) :4189-4193

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