Novel environment-friendly yellow pigments based on praseodymium(III) tungstate

被引：26
作者：
Bae, Byungseo [1 ]
Tamura, Shinji [1 ]
Imanaka, Nobuhito [1 ]
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan
来源：
CERAMICS INTERNATIONAL | 2017年 / 43卷 / 09期
关键词：
Inorganic yellow pigment; Environment-friendly; Trivalent cerium ion; Solid-state reaction method; LUMINESCENCE; PHOSPHORS; PR; SM;
D O I：
10.1016/j.ceramint.2017.02.103
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The novel environment-friendly inorganic yellow pigments, (Pr1-xCex)(2)W2O9+delta (0 <x <= 0.12) with the monoclinic structure, were synthesized and their color properties were investigated. The (Pr1-xCex)(2)W2O9+delta (0 < x <= 0.12) samples showed brilliant yellow color by doping trivalent Ce3+ into the Pr2W2O9 lattice due to the optical absorption in blue light region caused by the 4f -5d transition of Ce3+. According to the XPS and Rietveld analysis results, cerium ions in the crystal lattice have two different oxidation states of 3+ and 4+, in which the rate of each oxidation state is 58%:42%, and the Ce3+ and Ce4+ ions are preferentially occupied the PrO9 and the PrO8 polyhedral sites, respectively. Among the samples prepared, the (Pr0.90Ce0.10)(2)W2O9+delta pigment exhibited the most vivid yellow hue with high color durability for light and acid/base solutions.
引用
收藏
页码：7366 / 7368
页数：3
相关论文
共 10 条
  • [1] Luminescence properties of tungstates and molybdates phosphors: Illustration on ALn(MO4)2 compounds (A = alikaline cation, Ln = lanthanides, M = W, Mo)
    Benoit, Glorieux
    Veronique, Jubera
    Arnaud, Apheceixborde
    Alain, Garcia
    [J]. SOLID STATE SCIENCES, 2011, 13 (02) : 460 - 467
  • [2] Luminescence Characteristics of Pr3+ Ion Doped CaTiO3 Nanopowder Phosphors Synthesized by Solvothermal Method
    Chung, Jong Won
    Yang, Hyun Kyoung
    Moon, Byung Kee
    Choi, Byung Chun
    Jeong, Jung Hyun
    Kim, Jung Hwan
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2011, 11 (07) : 6208 - 6212
  • [3] Faulkner E.B., 2009, High Performance Pigments, V2nd
  • [4] Three-dimensional visualization in powder diffraction
    Izumi, Fujio
    Momma, Koichi
    [J]. APPLIED CRYSTALLOGRAPHY XX, 2007, 130 : 15 - 20
  • [5] Inorganic yellow-red pigments without toxic metals
    Jansen, M
    Letschert, HP
    [J]. NATURE, 2000, 404 (6781) : 980 - 982
  • [6] Up/down conversion luminescence and charge compensation investigation of Ca0.5Y1-x(WO4)2:xLn3+ (Ln = Pr, Sm, Eu, Tb, Dy, Yb/Er) phosphors
    Mahalingam, Venkatakrishnan
    Thirumalai, Jagannathan
    Krishnan, Rajagopalan
    Mantha, Srinivas
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2016, 152 : 172 - 180
  • [7] Novel and environmentally friendly (Bi,Ca,Zn)VO4 yellow pigments
    Masui, Toshiyuki
    Honda, Taihei
    Wendusu
    Imanaka, Nobuhito
    [J]. DYES AND PIGMENTS, 2013, 99 (03) : 636 - 641
  • [8] VESTA:: a three-dimensional visualization system for electronic and structural analysis
    Momma, Koichi
    Izumi, Fujio
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2008, 41 : 653 - 658
  • [9] REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES
    SHANNON, RD
    [J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1): : 751 - 767
  • [10] Dielectric properties of RE2W2O9 (RE = Pr, Sm-Gd) ceramics
    Urbanowicz, P.
    Piatkowska, M.
    Sawicki, B.
    Gron, T.
    Kukula, Z.
    Tomaszewicz, E.
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2015, 35 (15) : 4189 - 4193
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