Furfural production using ionic liquids: A review

被引:217
作者
Peleteiro, Susana
Rivas, Sandra
Luis Alonso, Jose
Santos, Valentin
Carlos Parajo, Juan [1 ]
机构
[1] Univ Vigo, Dept Chem Engn, Fac Sci, As Lagoas 32004, Ourense, Spain
关键词
Ionic liquids; Lignocellulosic materials; Biorefinery; Hemicelluloses; Furfural; 1-BUTYL-3-METHYLIMIDAZOLIUM HYDROGEN SULFATE; HIGH-YIELD CONVERSION; D-XYLOSE; LIGNOCELLULOSIC BIOMASS; PHASE DEHYDRATION; BIPHASIC MEDIA; ACID; PRETREATMENT; HYDROLYSIS; SUGARS;
D O I
10.1016/j.biortech.2015.12.017
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Furfural, a platform chemical with a bright future, is commercially obtained by acidic processing of xylan-containing biomass in aqueous media. Ionic liquids (ILs) can be employed in processed for furfural manufacture as additives, as catalysts and/or as reaction media. Depending on the IL utilized, externally added catalysts (usually, Lewis acids, Bronsted acids and/or solid acid catalysts) can be necessary to achieve high reaction yields. Oppositely, acidic ionic liquids (AILs) can perform as both solvents and catalysts, enabling the direct conversion of suitable substrates (pentoses, pentosans or xylan-containing biomass) into furfural. Operating in IL-containing media, the furfural yields can be improved when the product is continuously removed along the reaction (for example, by stripping or extraction), to avoid unwanted side-reactions leading to furfural consumption. These topics are reviewed, as well as the major challenges involved in the large scale utilization of ILs for furfural production. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:181 / 191
页数:11
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