Characterization of smoke for spacecraft fire safety

Conventional spacecraft smoke detectors are not optimized for detecting space smoke, which differs from that on Earth due to the fuel materials, burning conditions, particle formation/transformation processes, and lack of gravity. More effective smoke detectors can be developed with knowledge of smoke chemical compositions, size distributions, optical properties, and emission factors specific to spacecraft-relevant materials, e.g., Poly(methyl methacrylate) (PMMA), cotton, and Nomex (R) fabric. In normal gravity testing it is found that carbon is the main smoke component, with elemental carbon constituting similar to 90% of particle mass for flaming PMMA combustion and organic matter constituting greater than or similar to 80% of particle mass for other fuels and test conditions. Particles emitted from flaming PMMA are fractal-like soot agglomerates, different from the near spherical particles found for other fuels and burning conditions. Particle size distributions vary during the combustion process. When particle concentrations are near maximum, smoldering cotton generates bimodal number size distributions, while other fuels and test conditions exhibit unimodal lognormal number size distributions. Smoke particles from flaming PMMA combustion are black with single scattering albedos < 0.3, while particles from other burned materials demonstrate low light absorption, with single scattering albedos > 0.9 at 405-781 nm. Mass extinction coefficients are 7.8 m(2)/g for flaming PMMA and 2.7-4.2 m(2)/g for smoldering combustions at 632.8 nm. CO and PM2.5 emission factors are higher for smoldering than for flaming combustions, while CO2 emission factors are higher for flaming combustions.