Study on Phenolic-Resin/Carbon-fiber Ablation Composites Modified with Polyhedral Oligomeric Silsesquioxanes

被引:3
作者
Liu, Yu [1 ]
Lu, Zushun [1 ]
Chen, Xiaodong [2 ]
Wang, Di [1 ,3 ]
Liu, Jincheng [4 ]
Hu, Lijiang [1 ]
机构
[1] Harbin Inst Technol, Dept Chem, Sch Sci, Harbin 150001, Peoples R China
[2] Harbin Inst Technol, Sch Econ & Management, Harbin 150001, Peoples R China
[3] Northeast Forest Univ, Mat Sci & Engn Coll, Harbin 150040, Peoples R China
[4] Harbin Inst Technol, Natl Key Lab Tunable Laser Technol, Harbin 150001, Peoples R China
来源
2009 4TH IEEE INTERNATIONAL CONFERENCE ON NANO/MICRO ENGINEERED AND MOLECULAR SYSTEMS, VOLS 1 AND 2 | 2009年
关键词
Ablation; Modifier; Nanohybrid materials; Polyhedral oligomeric silsesquioxanes (POSS); Morphology; HYBRID NANOSTRUCTURAL BLOCKS; 3-DIMENSIONAL CONFIGURATIONS; HYDROLYTIC CONDENSATION; PROFILES;
D O I
10.1109/NEMS.2009.5068653
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
This study focuses on phenolic-resin/carbon-fiber (PR/CF) ablation composites modified with polyhedral oligomeric silsesquioxane (POSS) and tetraethoxysilicate (TEOS). Four nanomodifiers based on diglycidyl ether of biphenol A (DGEBA), TEOS-SiO2 (T-SiO2), octamethyl-POSS (Me-POSS) and phenyl-POSS (Ph-POSS) were prepared and employed to modify & PR/CF ablation materials. To compare ablation properties of the four modifiers, the correlation of the material structures and ablation properties are discussed with ablation tests and morphology measured by SEM. As a result, the former three is not viable as modifiers to enhance the ablation resistance; on the contrary, the properties of Ph-POSS show that it is suitable and more effective as a modifier for ablation materials.
引用
收藏
页码:605 / +
页数:2
相关论文
共 18 条
[1]   SILSESQUIOXANES [J].
BANEY, RH ;
ITOH, M ;
SAKAKIBARA, A ;
SUZUKI, T .
CHEMICAL REVIEWS, 1995, 95 (05) :1409-1430
[2]  
CHEN XD, 2008, 13 INT BIOT S, P755
[3]   Preparation, characterization, and properties of Novolac type phenolic/SiO2 hybrid organic-inorganic nanocomposite materials by sol-gel method [J].
Chiang, CL ;
Ma, CCM ;
Wu, DL ;
Kuan, HC .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (07) :905-913
[4]   Cagelike precursors of high-molar-mass silsesquioxanes formed by the hydrolytic condensation of trialkoxysilanes [J].
Eisenberg, P ;
Erra-Balsells, R ;
Ishikawa, Y ;
Lucas, JC ;
Mauri, AN ;
Nonami, H ;
Riccardi, CC ;
Williams, RJJ .
MACROMOLECULES, 2000, 33 (06) :1940-1947
[5]   Hardness and elastic modulus profiles of hybrid coatings [J].
Hu, LJ ;
Zhang, XW ;
Sun, Y ;
Williams, RJJ .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2005, 34 (01) :41-46
[6]   Characterization and coating properties of silsesquioxanes derived from the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane [J].
Hu, LJ ;
Zhang, XW ;
You, H ;
Liu, Y ;
Zhang, H ;
Sun, DZ .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (04) :1331-1335
[7]   Carbon/carbon composites derived from poly(ethylene oxide)-modified novolac-type phenolic resin: Microstructure and physical, and morphological properties [J].
Hung, AYC ;
Wang, FY ;
Yeh, SR ;
Chen, WJ ;
Ma, CCM .
JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 84 (08) :1609-1619
[8]  
KOO JH, 2004, P 45 AIAA ASME ASCE
[9]   Nanobuilding blocks based on the [OSiO1.5]x (x=6, 8, 10) octasilsesquioxanes [J].
Laine, RM .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (35-36) :3725-3744
[10]   Synthesis, morphology and properties of polydimethylsiloxane-modified allylated novolac/4,4′-bismaleimidodiphenylmethane [J].
Li, WW ;
Liu, F ;
Wei, LH ;
Zhao, T .
EUROPEAN POLYMER JOURNAL, 2006, 42 (03) :580-592