Molecular tectonics: gas adsorption and chiral uptake of (L)- and (D)-tryptophan by homochiral porous coordination polymers

被引：27

作者：

Asnaghi, Donata ^{[1
]}

Corso, Romain ^{[2
]}

Larpent, Patrick ^{[2
]}

Bassanetti, Irene ^{[1
]}

Jouaiti, Abdelaziz ^{[2
]}

Kyritsakas, Nathalie ^{[2
]}

Comotti, Angiolina ^{[1
]}

Sozzani, Piero ^{[1
]}

Hosseini, Mir Wais ^{[2
]}

机构：

[1] Univ Milano Bicocca, Dept Mat Sci, Via R Cozzi 55, Milan, Italy

[2] Univ Strasbourg, 7140 & icFRC, UMR UDS CNRS, Mol Tecton Lab, F-67000 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 42期

关键词：

METAL-ORGANIC FRAMEWORKS; ENANTIOSELECTIVE ADSORPTION; METHANE STORAGE; ENANTIOMER SEPARATION; ROOM-TEMPERATURE; NETWORKS; SORPTION; HYDROCARBONS; CHEMISTRY; CATALYSIS;

D O I：

10.1039/c7cc01554b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Combinations of two enantiomerically pure organic tectons 1 and 3 with either Zn(II) or Cu(II) cations lead to the formation of four homochiral 3D networks among which two, 1-Cu and 3-Cu, are robust porous crystals displaying homochiral cavities and permanent microporosity. 3-Cu porous crystals capture 66% and 20% of L-and D-tryptophan, respectively, after 30 min of adsorption.

引用

页码：5740 / 5743

页数：4

共 56 条

[1] A NEW TYPE OF INFINITE 3D POLYMERIC NETWORK CONTAINING 4-CONNECTED, PERIPHERALLY LINKED METALLOPORPHYRIN BUILDING-BLOCKS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) :3606-3607

[2]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[3]

2-Z

[4] Permanent microporosity and enantioselective sorption in a chiral open framework [J].

Bradshaw, D ;

Prior, TJ ;

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114

[5]

Chen L, 2014, NAT MATER, V13, P954, DOI [10.1038/nmat4035, 10.1038/NMAT4035]

[6] Porous dipeptide crystals as selective CO2 adsorbents: experimental isotherms vs. grand canonical Monte Carlo simulations and MAS NMR spectroscopy [J].

Comotti, Angiolina ;

Fraccarollo, Alberto ;

Bracco, Silvia ;

Beretta, Mario ;

Distefano, Gaetano ;

Cossi, Maurizio ;

Marchese, Leonardo ;

Riccardi, Claudia ;

Sozzani, Piero .

CRYSTENGCOMM, 2013, 15 (08) :1503-1507

[7] Competitive growth of crystals in vanadium-chromium slag [J].

Diao, Jiang ;

Zhou, Wang ;

Gu, Pan ;

Ke, Zhaoqun ;

Qiao, Yong ;

Xie, Bing .

CRYSTENGCOMM, 2016, 18 (33) :6272-6281

[8] Application of TLC, HPLC and GC methods to the study of amino acid and peptide enantiomers: a review [J].

Dolowy, Malgorzata ;

Pyka, Alina .

BIOMEDICAL CHROMATOGRAPHY, 2014, 28 (01) :84-101

[9] A new microporous metal-organic framework with potential for highly selective separation methane from acetylene, ethylene and ethane at room temperature [J].

Duan, Xing ;

Zhang, Qi ;

Cai, Jianfeng ;

Cui, Yuanjing ;

Wu, Chuande ;

Yang, Yu ;

Qian, Guodong .

MICROPOROUS AND MESOPOROUS MATERIALS, 2014, 190 :32-37

[10] A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity [J].

Dybtsev, DN ;

Nuzhdin, AL ;

Chun, H ;

Bryliakov, KP ;

Talsi, EP ;

Fedin, VP ;

Kim, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :916-920

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