Process monitoring of polymers by in-line ATR-IR, NIR and Raman spectroscopy and ultrasonic measurements

被引：38

作者：

Fischer, Dieter ^{[1
]}

Sahre, Karin ^{[1
]}

Abdelrhim, Mona ^{[1
]}

Voit, Brigitte ^{[1
]}

Sadhu, Veera B. ^{[1
]}

Pionteck, Juergen ^{[1
]}

Komber, Hartmut ^{[1
]}

Hutschenreuter, Jan ^{[1
]}

机构：

[1] Leibniz Inst Polymer Res Dresden, D-01069 Dresden, Germany

来源：

COMPTES RENDUS CHIMIE | 2006年 / 9卷 / 11-12期

关键词：

process monitoring; in-line analysis; polymers; spectroscopy; ultrasonic; extrusion monitoring;

D O I：

10.1016/j.crci.2006.06.006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aim of the present work is to show that spectroscopic and ultrasonic methods are powerful in situ methods for monitoring polymerization processes and for the determination of the composition of polymer blends and additives during extrusion. Quantitative analysis carried out with chemometric methods can determine the composition of multicomponent polymer mixtures and predict real world samples in real-time during extrusion. Examples are the modification of hyperbranched poly(urea-urethane)s, the polymerization of MMA, the real-time determination of flame retardants in PA, and the determination of the composition of the blend PE/PS.

引用

页码：1419 / 1424

页数：6

共 22 条

[1] Combination of NIR, Raman, ultrasonic and dielectric spectroscopy for in-line monitoring of the extrusion process
Alig, I
Fischer, D
Lellinger, D
Steinhoff, B
[J]. MACROMOLECULAR SYMPOSIA, 2005, 230 : 51 - 58
[2] ALIG I, DKI DARMSTADT
[3] [Anonymous], 1989, MULTIVARIATE CALIBRA
[4] Vibrational spectroscopic and ultrasound analysis for in-process characterization of high-density polyethylene/polypropylene blends during melt extrusion
Barnes, SE
Brown, EC
Sibley, MG
Edwards, HGM
Scowen, IJ
Coates, PD
[J]. APPLIED SPECTROSCOPY, 2005, 59 (05) : 611 - 619
[5] Measurement of the Irganox content in polypropylene polymers during extrusion
Becker, W
Eisenreich, N
[J]. JOURNAL OF NEAR INFRARED SPECTROSCOPY, 2005, 13 (03) : 147 - 154
[6] Brereton RichardG., 2003, CHEMOMETRICS
[7] CARDENASVALENCI.AM, 2003, IN SITU SPECTROSCOPY, P83
[8] Chalmers JM, 2000, SHEFF ANALY CHEM, P1
[9] CHAU F, 2004, CHEMOMETRICS
[10] Robust on-line measurement of conversion and molecular weight using NIR spectroscopy during solution polymerization
Cherfi, A
Fevotte, G
Novat, C
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 85 (12) : 2510 - 2520

← 1 2 3 →