Palladium-Catalyzed Dehydrogenative Coupling of Furans with Styrenes

被引：65

作者：

Aouf, Chahinez ^{[1
]}

Thiery, Emilie ^{[1
]}

Le Bras, Jean ^{[1
]}

Muzart, Jacques ^{[1
]}

机构：

[1] Univ Reims, Inst Chim Mol Reims, CNRS, UMR 6229,UFR Sci Exactes & Nat, F-51687 Reims 2, France

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 18期

关键词：

C-H ALKENYLATION; FREE NH-INDOLES; BOND FUNCTIONALIZATION; MOLECULAR-OXYGEN; OLEFINS; ARENES; ACTIVATION; OXIDANT; C3-ALKENYLATION; THIOPHENES;

D O I：

10.1021/ol901570p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under palladium(II)-catalyzed and oxidative conditions, the coupling of furans with styrenes leads to the formation of Heck-type products in medium to good yields. The reaction is highly regio- and stereoselective, giving trans-olefins predominantly.

引用

页码：4096 / 4099

页数：4

共 35 条

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