The effect of reaction temperature on the particle size, structure and magnetic properties of coprecipitated CoFe2O4 nanoparticles

被引:368
作者
Qu, Yuqiu
Yang, Haibin [1 ]
Yang, Nan
Fan, Yuzun
Zhu, Hongyang
Zou, Guangtian
机构
[1] Jilin Univ, Natl Lab Superhard Mat, Changchun 130012, Peoples R China
[2] Henan Polytech Univ, Sch Mat Sci & Engn, Jiaozuo 454003, Peoples R China
关键词
cobalt ferrite; nanoparticles; coprecipitation; magnetic properties; coercivity;
D O I
10.1016/j.matlet.2006.03.055
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Magnetic nanoparticles of cobalt ferrite have been synthesized at different temperatures without any subsequent heat treatment. The particle size, crystal structure and magnetic properties of as-synthesized particles were investigated by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, Raman spectroscopy and vibrating sample magnetometer. The nanoparticles are of cubic spinel structure and equiaxial shape. The average size of nanoparticles increases with the increase of reaction temperature. Magnetic properties of nanoparticles show strong dependence on the particle size. A maximum coercivity of 3267 Oe and a maximum remanence ratio of 0.58 are obtained from the sample synthesized at 80 degrees C. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:3548 / 3552
页数:5
相关论文
共 25 条
[1]   Magnetization and Mossbauer study of cobalt ferrite particles from nanophase cobalt iron carbonate [J].
Ahn, Y ;
Choi, EJ ;
Kim, S ;
Ok, HN .
MATERIALS LETTERS, 2001, 50 (01) :47-52
[2]   The continuous hydrothermal synthesis of nano-particulate ferrites in near critical and supercritical water [J].
Cabañas, A ;
Poliakoff, M .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (05) :1408-1416
[3]   Spindly cobalt ferrite nanocrystals: Preparation, characterization and magnetic properties [J].
Cao, XB ;
Gu, L .
NANOTECHNOLOGY, 2005, 16 (02) :180-185
[4]   Synthesis of size-controlled cobalt ferrite particles with high coercivity and squareness ratio [J].
Chinnasamy, CN ;
Senoue, M ;
Jeyadevan, B ;
Perales-Perez, O ;
Shinoda, K ;
Tohji, K .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 263 (01) :80-83
[5]   Growth dominant co-precipitation process to achieve high coercivity at room temperature in CoFe2O4 nanoparticles [J].
Chinnasamy, CN ;
Jeyadevan, B ;
Perales-Perez, O ;
Shinoda, K ;
Tohji, K ;
Kasuya, A .
IEEE TRANSACTIONS ON MAGNETICS, 2002, 38 (05) :2640-2642
[6]   CaFe2O4 thin films grown on (100)MgO substrates using pulsed laser deposition [J].
Dorsey, PC ;
Lubitz, P ;
Chrisey, DB ;
Horwitz, JS .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (08) :6338-6340
[7]   Photomagnetism and structure in cobalt ferrite nanoparticles [J].
Giri, AK ;
Kirkpatrick, EM ;
Moongkhamklang, P ;
Majetich, SA ;
Harris, VG .
APPLIED PHYSICS LETTERS, 2002, 80 (13) :2341-2343
[8]   Effect of light on the magnetic properties of cobalt ferrite nanoparticles [J].
Giri, AK ;
Pellerin, K ;
Pongsaksawad, W ;
Sorescu, M ;
Majetich, SA .
IEEE TRANSACTIONS ON MAGNETICS, 2000, 36 (05) :3029-3031
[9]   Magnetic properties and Mossbauer spectra of nanosized CoFe2O4 powders [J].
Grigorova, M ;
Blythe, HJ ;
Blaskov, V ;
Rusanov, V ;
Petkov, V ;
Masheva, V ;
Nihtianova, D ;
Martinez, LM ;
Munoz, JS ;
Mikhov, M .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1998, 183 (1-2) :163-172
[10]   Synthesis of cobalt ferrite nanocrystallites by the forced hydrolysis method and investigation of their magnetic properties [J].
Hanh, N ;
Quy, OK ;
Thuy, NP ;
Tung, LD ;
Spinu, L .
PHYSICA B-CONDENSED MATTER, 2003, 327 (2-4) :382-384