A supramolecular optic receptor for selective recognition CDP in neutral aqueous solution

被引：3

作者：

Shang, Xue-Fang ^{[1
,2
]}

Yu, Jie ^{[1
]}

Lin, Hua-Kuan ^{[2
]}

机构：

[1] Xinxiang Med Univ, Dept Chem, Xinxiang Henan, Peoples R China

[2] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 24期

基金：

中国国家自然科学基金;

关键词：

Optic receptor; Nucleotides; Recognition; Supramolecular interaction; MOLECULAR RECOGNITION; ANION RECOGNITION; ATP; PHENANTHROLINE; BEARING; BINDING; NUCLEOTIDES; METAL; GTP; HYDROLYSIS;

D O I：

10.1080/00958970903215107

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We designed and synthesized a Cu-coordination complex based on a seven-membered amide cycle and studied its binding ability with nucleotides (cytidine 5'-monophosphate (CMP), cytidine 5'-diphosphate (CDP), cytidine 5'-triphosphate (CTP), cytidine d-5'-monophosphate (dCMP), and thymidine d-5'-monophosphate (dTMP)) by UV-Vis spectroscopy. Results indicate that the compound shows the highest binding ability with CDP among the studied nucleotides and can selectively and strongly bind nucleotides in neutral aqueous solution. The compound can be used as optical receptor for the detection of CDP.

引用

页码：3951 / 3960

页数：10

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