Single Metal Atom Photocatalysis

被引：197

作者：

Wang, Bin ^{[1
,2
]}

Cai, Hairui ^{[1
]}

Shen, Shaohua ^{[2
]}

机构：

[1] Xi An Jiao Tong Univ, Sch Sci, Xian 710049, Shaanxi, Peoples R China

[2] Xi An Jiao Tong Univ, Int Res Ctr Renewable Energy, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China

来源：

SMALL METHODS | 2019年 / 3卷 / 09期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

CO2; reduction; photocatalysis; photocatalytic degradation; single metal atoms; water splitting; HIGHLY DISPERSED NOBLE; HYDROGEN EVOLUTION; ACTIVE-SITES; CO OXIDATION; SUPPORTED SINGLE; BASE METALS; CATALYST; PLATINUM; WATER; NANOPARTICLES;

D O I：

10.1002/smtd.201800447

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photocatalysis suffers from rapid recombination of photoexcited charge carriers and limited active sites for the catalytic reactions, resulting in unsatisfactory performances that are far from practical application. Single metal atom catalysts not only increase the number of active sites due to the maximum atom-utilization efficiency, but also enhance the intrinsic activity of each active site because of their unique geometric and electronic features. Furthermore, single metal atom catalysts provide a platform for photocatalysis research on the atomic level. This review discusses the unique characteristics, including geometric and electronic properties, of single metal atom catalysts, summarizes their synthesis strategies, and reviews their most recent development in photocatalysis. Finally, the challenges of single metal catalysts for both fundamental research and practical application are highlighted.

引用

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